Decoherence in an anharmonic oscillator coupled to a thermal environment: A semiclassical forward-backward approach

被引:31
作者
Elran, Y [1 ]
Brumer, P
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
[2] Univ Toronto, Ctr Quantum Informat & Quantum Control, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1063/1.1766009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The decoherence of an anharmonic oscillator in a thermal harmonic bath is examined via a semiclassical approach. A computational strategy is presented and exploited to calculate the time dependence of the purity and the decay of individual matrix elements in the energy representation for a variety of initial states. The time dependence of the decoherence is found to depend on the temperature of the bath, the coupling strength, the initial state of the oscillator, and the choice of quantity measuring the decoherence. Recurrences in the purity and in the off-diagonal matrix elements are observed, as well as the collapse of these matrix elements to the diagonal, providing evidence for the retention of quantum coherence for time scales longer than that indicated by the purity. The results are used to analyze the utility of the Caldeira-Leggett and Redfield models of decoherence and to assess the dependence of dephasing rates on the degree of structure in phase space. In several cases we find that the dephasing dynamics can be described as an initial Zeno-effect regime, followed by a Caldeira-Leggett region, followed by recurrences. (C) 2004 American Institute of Physics.
引用
收藏
页码:2673 / 2684
页数:12
相关论文
共 72 条
[1]  
Abramowitz M., 1965, Handbook of Mathematical Functions
[2]   Deconstructing decoherence [J].
Anglin, JR ;
Paz, JP ;
Zurek, WH .
PHYSICAL REVIEW A, 1997, 55 (06) :4041-4053
[3]   Semiclassical molecular dynamics simulations of ultrafast photodissociation dynamics associated with the Chappuis band of ozone [J].
Batista, VS ;
Miller, WH .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (02) :498-510
[4]  
BERNE BJ, 1986, ANNU REV PHYS CHEM, V37, P401
[5]   Onset of decoherence:: Six-wave mixing measurements of vibrational decoherence on the excited electronic state of I2 in solid argon [J].
Bihary, Z ;
Karavitis, M ;
Apkarian, VA .
JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (17) :8144-8156
[6]  
Blum K., 2012, DENSITY MATRIX THEOR
[7]  
Breuer H.-P., 2002, THEORY OPEN QUANTUM
[8]   Multiconfigurational system-bath dynamics using Gaussian wave packets: Energy relaxation and decoherence induced by a finite-dimensional bath [J].
Burghardt, I ;
Nest, M ;
Worth, GA .
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (11) :5364-5378
[9]   PATH INTEGRAL APPROACH TO QUANTUM BROWNIAN-MOTION [J].
CALDEIRA, AO ;
LEGGETT, AJ .
PHYSICA A, 1983, 121 (03) :587-616
[10]   Semiclassical initial value approach for chaotic long-lived dynamics [J].
Campolieti, G ;
Brumer, P .
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (08) :2999-3003