Stimuli-responsive metallo-supramolecular polymer films: design, synthesis and device fabrication

被引：134

作者：

Higuchi, Masayoshi ^{[1
,2
]}

机构：

[1] Natl Inst Mat Sci, Elect Funct Mat Grp, Tsukuba, Ibaraki 3050044, Japan

[2] Japan Sci & Technol Agcy, CREST, Tokyo 1028666, Japan

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2014年 / 2卷 / 44期

关键词：

PRUSSIAN-BLUE; ELECTROCHROMIC PROPERTIES; COORDINATION POLYMERS; HYBRID POLYMERS; BIS-TERPYRIDINES; CONDUCTIVITY; COPPER(I); BISTERPYRIDINES; IONS; 1,10-PHENANTHROLINE;

D O I：

10.1039/c4tc00689e

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Metallo-supramolecular polymers, which were synthesized via the 1 : 1 complexation of metal ions with ditopic organic ligands, showed unique electro- and photo-chemical properties based on the metal-ligand or metal-metal interactions. Fe(II)-, Ru(II)-and Cu(II)-based metallo-supramolecular polymer films exhibited reversible electrochromic behaviour and electrochromic display devices were successfully fabricated. A polymer containing both Fe(II) and Ru(II) ions exhibited multi-colour electrochromic properties. Ionic conductivity of a Ni(II)-based polymer film was significantly enhanced with increasing humidity, and real-time humidity sensing was realized by utilizing the polymer film. A Eu(III)-based polymer showed vapoluminescence. Reversible switching of emission was achieved in the polymer with Fe(II) and Eu(III) ions introduced in an alternating manner.

引用

页码：9331 / 9341

页数：11

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