Stimuli-responsive metallo-supramolecular polymer films: design, synthesis and device fabrication

被引：134
|
作者：
Higuchi, Masayoshi [1 ,2 ]
机构：
[1] Natl Inst Mat Sci, Elect Funct Mat Grp, Tsukuba, Ibaraki 3050044, Japan
[2] Japan Sci & Technol Agcy, CREST, Tokyo 1028666, Japan
来源：
JOURNAL OF MATERIALS CHEMISTRY C | 2014年 / 2卷 / 44期
关键词：
PRUSSIAN-BLUE; ELECTROCHROMIC PROPERTIES; COORDINATION POLYMERS; HYBRID POLYMERS; BIS-TERPYRIDINES; CONDUCTIVITY; COPPER(I); BISTERPYRIDINES; IONS; 1,10-PHENANTHROLINE;
D O I：
10.1039/c4tc00689e
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Metallo-supramolecular polymers, which were synthesized via the 1 : 1 complexation of metal ions with ditopic organic ligands, showed unique electro- and photo-chemical properties based on the metal-ligand or metal-metal interactions. Fe(II)-, Ru(II)-and Cu(II)-based metallo-supramolecular polymer films exhibited reversible electrochromic behaviour and electrochromic display devices were successfully fabricated. A polymer containing both Fe(II) and Ru(II) ions exhibited multi-colour electrochromic properties. Ionic conductivity of a Ni(II)-based polymer film was significantly enhanced with increasing humidity, and real-time humidity sensing was realized by utilizing the polymer film. A Eu(III)-based polymer showed vapoluminescence. Reversible switching of emission was achieved in the polymer with Fe(II) and Eu(III) ions introduced in an alternating manner.
引用
收藏
页码：9331 / 9341
页数：11
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