Chloride threshold value and initial corrosion time of steel bars in concrete exposed to saline soil environments

被引：46

作者：

Yang, Deqiang ^{[1
]}

Yan, Changwang ^{[2
]}

Zhang, Ju ^{[2
]}

Liu, Shuguang ^{[1
,2
]}

Li, Jie ^{[2
]}

机构：

[1] Inner Mongolia Univ Technol, Sch Mat Sci & Engn, Hohhot 010051, Peoples R China

[2] Inner Mongolia Univ Technol, Sch Min & Technol, 49 Aimin St, Hohhot 010051, Peoples R China

来源：

CONSTRUCTION AND BUILDING MATERIALS | 2021年 / 267卷

基金：

中国国家自然科学基金;

关键词：

Saline soil; Chloride threshold value; Initial corrosion time; EIS; Sulfate; Chloride diffusion; REINFORCEMENT CORROSION; DIFFUSION-COEFFICIENT; PORE SOLUTIONS; SULFATE; LEVEL; DURABILITY; PENETRATION; PREDICTION; MECHANISM; PLAIN;

D O I：

10.1016/j.conbuildmat.2020.120979

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

Saline soil is widely distributed in Western China. Its main components have the characteristics of high concentration and many kinds of ions, which pose a serious threat to the service life of reinforced concrete in this area. Therefore, it is of practical significance to determine the initial corrosion time and the chloride threshold value (CTV) of steel bars. In this research, the electrochemical impedance spectroscopy (EIS) method was used to determine the initial corrosion time and the CTV of steel bars immersed in saline soil simulation solutions, and the influence of sulfate and other ions on the initial corrosion time and the CTV of the steel bars was analyzed, as well as the influence mechanism. Based on Fick's second diffusion law, considering the time-dependencies of the chloride diffusion coefficient and the surface chloride content, a prediction model for the initial corrosion time of a steel bar in concrete was established. The results showed that compared with the solution containing only chloride and the solution containing low concentration of sulfate, the initial corrosion time of steel bars in saline soil simulation solution was significantly longer, and the CTV was lower. The sulfate had an obvious inhibited effect on the diffusion of chloride, the corrosion products of sulfate could fill the pores of concrete, affect the microstructure of the transition zone and concrete resistance, and caused the initial corrosion time of the steel bars to increase. other ions in the simulation solution also inhibited the diffusion of chloride, HCO3 ion reduced the pH value of concrete pore solution and made the CTV of steel bars decrease. The prediction model established in this research was in good agreement with the actual situation, which can provide experimental evidence for the service life prediction of reinforced concrete structures in a saline soil environment. In order to prolong the initial corrosion time of the reinforced concrete in a saline soil simulation solution, in addition to increasing the thickness of the concrete protective layer, other anti-corrosion measures were also needed. (C) 2020 Elsevier Ltd. All rights reserved.

引用

页数：12

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