Olefin metathesis

被引：1262
作者：
Grubbs, RH [1 ]
机构：
[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Lab Chem Synth, Pasadena, CA 91125 USA
来源：
TETRAHEDRON | 2004年 / 60卷 / 34期
关键词：
olefin metathesis; polymerization; carbene;
D O I：
10.1016/j.tet.2004.05.124
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Olefin metathesis has become a tool for synthetic organic and polymer chemists. Well-defined, functional group tolerant catalysts have allowed these advances. A discussion of the evolution of mechanistic understanding and early catalyst developments is followed by a description of recent advances in ruthenium based olefin metathesis catalysts. Catalysts improvements have led to new applications in ring closing metathesis, cross metathesis and materials synthesis. (C) 2004 Published by Elsevier Ltd.
引用
收藏
页码：7117 / 7140
页数：24
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