High catalytic activity and selectivity in hydrosilylation of new Pt(II) metallosupramolecular complexes based on ambidentate ligands

被引：24

作者：

Walczak, Anna ^{[1
,2
]}

Stachowiak, Hanna ^{[1
]}

Kurpik, Gracjan ^{[1
,2
]}

Kazmierczak, Joanna ^{[1
]}

Hreczycho, Grzegorz ^{[1
]}

Stefankiewicz, Artur R. ^{[1
,2
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Umultowska 89b, PL-61614 Poznan, Poland

[2] Adam Mickiewicz Univ, Ctr Adv Technol, Umultowska 89b, PL-61614 Poznan, Poland

来源：

JOURNAL OF CATALYSIS | 2019年 / 373卷

关键词：

Pt(II) complexes; Supramolecular chemistry; Catalysis; Hydrosilylation; Functionalized olefins; ALKENE HYDROSILYLATION; PLATINUM; HYDROGEN; PRINCIPLES; STYRENE; BEARING; OLEFINS; WATER;

D O I：

10.1016/j.jcat.2019.03.041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two new air- and water-stable Pt(II) metallosupramolecular complexes based on ambidentate ligands have been designed, synthesized and fully characterized. The structure of complexes has been determined by various analytical techniques including NMR spectroscopy and TOF-MS. Additionally, the single crystal structure of 2 was determined by X-ray diffraction. The catalytic activity of these complexes in hydrosilylation has been investigated, establishing that both have similar high activity and selectivity within a broad scope of structurally distinct olefins and hydrosilanes. (C) 2019 Elsevier Inc. All rights reserved.

引用

页码：139 / 146

页数：8

共 50 条

[31] Synthesis and catalytic activity of nickel(II) complexes containing NCN pincer ligands
Nair, Ashwin G.
McBurney, Roy T.
Gatus, Mark R. D.
Walker, D. Barney
Bhadbhade, Mohan
Messerle, Barbara A.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 845 : 63 - 70
[32] Organochalcogen ligands and their palladium(II) complexes: Synthesis to catalytic activity for Heck coupling
Kumar, Arun
Rao, Gyandshwar Kumar
Singh, Ajai K.
RSC ADVANCES, 2012, 2 (33) : 12552 - 12574
[33] EFFECT OF LIGANDS ON CATALYTIC ACTIVITY OF PD(II) COMPLEXES IN CARBONYLATION REACTION OF ACETYLENE
ORLOVA, IA
ALEKSEEVA, NF
TROITSKAYA, AD
TEMKIN, ON
ZHURNAL OBSHCHEI KHIMII, 1979, 49 (07): : 1601 - 1605
[34] Synthesis of a series of new platinum organometallic complexes derived from bidentate Schiff-base ligands and their catalytic activity in the hydrosilylation and dehydrosilylation of styrene
Lachachi, M. Belhadj
Benabdallah, Tayeb
Aguiar, Pedro M.
Youcef, M. Hadj
Whitwood, Adrian C.
Lynam, Jason M.
DALTON TRANSACTIONS, 2015, 44 (26) : 11919 - 11928
[35] Synthesis, structure and catalytic activity of thioether-phosphane complexes of Pd(II) and Pt(II)
Dilworth, JR
von Beckh, CAM
Pascu, SI
DALTON TRANSACTIONS, 2005, (12) : 2151 - 2161
[36] Dicopper Complexes with Anthyridine-Based Ligands: Coordination and Catalytic Activity
Huang, Da-wei
Liu, Yi-Hung
Peng, Shie-Ming
Liu, Shiuh-Tzung
ORGANOMETALLICS, 2016, 35 (02) : 151 - 158
[37] Pt(II) complexes bearing P,N-donor ligands as catalysts in chemoselective hydrosilylation, hydrogermylation, and hydroboration of terminal alkenes
Stachowiak-Dluzynska, Hanna
Gruszczynski, Marcin
Kubicki, Maciej
Hreczycho, Grzegorz
JOURNAL OF CATALYSIS, 2024, 433
[38] Synthesis and cytostatic activity of Pt(II) complexes of intramolecularly coordinated phosphine and stibine ligands
Reznicek, Tomas
Dostal, Libor
Ruzicka, Ales
Vinklarek, Jaromir
Rezacova, Martina
Jambor, Roman
APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (05) : 237 - 245
[39] SYNTHESIS OF NEW Pt(II) COMPLEX BEARING ORGANOSELENIUM LIGANDS AND EVALUATION OF CYTOTOXIC ACTIVITY OF SOME STRUCTURALLY RELATED Pd(II) COMPLEXES
Radenkovic, Ninko
Kostic, Marina D.
Dordevic, Natasa Z.
Dolicanin, Zana C.
Soldatovic, Tanj A., V
Zivanovic, Marko N.
Divac, Vera M.
MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, 2020, 39 (01) : 59 - 64
[40] Synthesis, structure, and catalytic activity of group 4 complexes with new chiral binaphthyldiamine-based ligands
Xiang, Li
Zhang, Furen
Zhang, Jiaxin
Song, Haibin
Zi, Guofu
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (05) : 666 - 670

← 1 2 3 4 5 →