High catalytic activity and selectivity in hydrosilylation of new Pt(II) metallosupramolecular complexes based on ambidentate ligands

被引：24

作者：

Walczak, Anna ^{[1
,2
]}

Stachowiak, Hanna ^{[1
]}

Kurpik, Gracjan ^{[1
,2
]}

Kazmierczak, Joanna ^{[1
]}

Hreczycho, Grzegorz ^{[1
]}

Stefankiewicz, Artur R. ^{[1
,2
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Umultowska 89b, PL-61614 Poznan, Poland

[2] Adam Mickiewicz Univ, Ctr Adv Technol, Umultowska 89b, PL-61614 Poznan, Poland

来源：

JOURNAL OF CATALYSIS | 2019年 / 373卷

关键词：

Pt(II) complexes; Supramolecular chemistry; Catalysis; Hydrosilylation; Functionalized olefins; ALKENE HYDROSILYLATION; PLATINUM; HYDROGEN; PRINCIPLES; STYRENE; BEARING; OLEFINS; WATER;

D O I：

10.1016/j.jcat.2019.03.041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two new air- and water-stable Pt(II) metallosupramolecular complexes based on ambidentate ligands have been designed, synthesized and fully characterized. The structure of complexes has been determined by various analytical techniques including NMR spectroscopy and TOF-MS. Additionally, the single crystal structure of 2 was determined by X-ray diffraction. The catalytic activity of these complexes in hydrosilylation has been investigated, establishing that both have similar high activity and selectivity within a broad scope of structurally distinct olefins and hydrosilanes. (C) 2019 Elsevier Inc. All rights reserved.

引用

页码：139 / 146

页数：8

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