Synthesis, spectral characterization, and evaluation of antimicrobial activity of O,O-alkanediyl S-(N-phthalimidomethyl) dithiophosphates and zinc bis(O,O-alkanediyl) dithiophosphates

被引：4
|
作者：
Rastogi, Rupali [1 ]
Gupta, Srasti [1 ]
Tarannum, Nazia [2 ]
Agarwal, Ranu [2 ]
Butcher, R. J. [3 ]
机构：
[1] ITM Univ, Dept Chem, AH 43,NH 75,Jhansi Rd, Gwalior 474001, MP, India
[2] Chaudhary Charan Singh Univ, Dept Chem, Meerut, Uttar Pradesh, India
[3] Howard Univ, Dept Chem, Washington, DC 20059 USA
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2017年 / 192卷 / 03期
关键词：
Phthalimidomethyl; zinc; ammonium; dithiophosphates; X-ray structure; antimicrobial activity; ALKYLENE DITHIOPHOSPHATES; ORGANIC DERIVATIVES; COMPLEXES; CRYSTAL; ANTIMONY; ACID;
D O I：
10.1080/10426507.2016.1237949
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of novel dithiophosphate derivatives has been achieved. Two O,O-alkanediyl S-(N-phthalimidomethyl) dithiophosphates and two Zinc bis(O,O-alkanediyl) dithiophosphates are synthesized by an easy and facile chemical synthetic route. Zinc bis[O,O-(2-methylpentane-2,4-diyl) dithiophosphate] L-1, Zinc bis[O,O-(2-ethylhexane-1,3-diyl) dithiophosphate] L-2, O,O-(2-methylpentane-2,4-diyl) S-(N-phthalimidomethyl) dithiophosphate L-3 and O,O-(2-ethylhexane-1,3-diyl) S-(N-phthalimidomethyl) dithiophosphate L-4 are synthesized from the respective ammonium salts. Compounds L-1, L-2, L-3, and L-4 are characterized by (CHN) elemental analysis, ESI mass, FT-IR, H-1, C-13, and P-31 NMR techniques. The crystal structure of ammonium O,O-(2-methylpentane-2,4-diyl) dithiophosphate is discussed. L-1, L-2, L-3, and L-4 were evaluated for antimicrobial activity. It was found that the phthalimide derivatives L-3 and L-4 showed much better antifungal potential against some species of fungus. The Zinc dithiophosphates L-1 and L-2 showed good antibacterial activity against Bacillus cereus and Escherichia coli.
引用
收藏
页码：300 / 306
页数：7
相关论文
共 38 条
  • [31] Synthesis, Spectroscopic Characterization, Thermal Investigation and Antimicrobial Activity of S, O and N-Donor Heterocyclic Schiff Base Ligands and their Co(II), Cd(II), Hg(II), Fe(III) and UO2(II) Metal Complexes
    El-Shafiey, Zeinab A.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2010, 53 (01): : 137 - 162
  • [32] Stereospecific ligands and their complexes IX: Synthesis, characterization and antimicrobial activity of ethyl esters of (S,S)-ethylenediamine-N,N′-di-2-propanoic and (S,S)-ethylenediamine-N,N′-di-2-(3-methyl)-butanoic acids and corresponding platinum(IV) complexes: Crystal structure of tetrachloride-(O,O′-diethyl-(S,S)-ethylenediamine-N,N′-di-2-propanoato)-platinum(IV), [PtCl4(det-S,S-eddp)]
    Stankovic, Milena Z.
    Radic, Gordana P.
    Glodovic, Verica V.
    Radojevic, Ivana D.
    Stefanovic, Olgica D.
    Comic, Ljiljana R.
    Klisuric, Olivera R.
    Djinovic, Vesna M.
    Trifunovic, Srecko R.
    POLYHEDRON, 2011, 30 (13) : 2203 - 2209
  • [33] Synthesis, spectral characterization, optical properties and X-ray structural studies of S centrosymmetric N2S2 or N2S2O2 donor Schiff base ligand and its binuclear transition metal complexes
    El-Gammal, O. A.
    Saad, D. A.
    Al-Hossainy, A. F.
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1244
  • [34] PART XVI - STEREOSPECIFIC LIGANDS AND THEIR COMPLEXES. SYNTHESIS, CHARACTERIZATION AND IN VITRO ANTIPROLIFERATIVE ACTIVITY OF NEW PLATINUM(IV) COMPLEXES WITH SOME O,O'-DIALKYL ESTERS OF (S,S)-ETHYLENEDIAMINE-N,N'-DI-2-PROPANOIC ACID AGAINST BREAST CANCER (MDA-MB-231) AND COLON CANCER (HCT-116 AND SW-480) CELL LINES
    Jevtic, Verica V.
    Radic, Gordana P.
    Seklic, Dragana S.
    Zivanovic, Marko N.
    Markovic, Snezana D.
    Trifunovic, Srecko R.
    MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, 2014, 33 (01) : 53 - 58
  • [35] Synthesis and crystal structure of trans-tetraaqua-bis(3-(((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)ammonio) propanoato-κO)zinc(II) tetrahydrate, C38H48N2O26S2Zn
    Chen, Hai-Lin
    Pan, Li-Wei
    Qin, Yong-Ling
    Xie, Yan-Jun
    Zhang, Peng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (02): : 217 - 219
  • [36] Dinuclear Zn(II) and tetranuclear Co(II) complexes of a tetradentate N2O2 Schiff base ligand: Synthesis, crystal structure, characterization, DFT studies, cytotoxicity evaluation, and catalytic activity toward benzyl alcohol oxidation
    Sanatkar, Tahereh Hosseinzadeh
    Khorshidi, Alireza
    Janczak, Jan
    APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (04)
  • [37] Stereospecific ligands and their complexes. Part XXI. Synthesis, characterization, circular dichroism and antimicrobial activity of cobalt(III) complexes with some edda-type of ligands. Crystal structure of potassium-Δ-(-)589-s-cis-oxalato-(S,S)-ethylenediamine-N,N′-di-(2-propanoato)-cobaltate(III)-semihydrate, K-Δ-(-)589-s-cis-[Co(S,S-eddp)(ox)]•0.5H2O
    Ilic, Dragoslav
    Jevtic, Verica V.
    Vasojevic, Miorad M.
    Jelic, Miodrag Z.
    Radojevic, Ivana D.
    Comic, Ljiljana R.
    Novakovic, Sladana B.
    Bogdanovic, Goran A.
    Potocnak, Ivan
    Trifunovic, Srecko R.
    POLYHEDRON, 2015, 85 : 1 - 9
  • [38] Synthesis, characterization and antimicrobial activity of novel platinum(IV) and palladium(II) complexes with meso-1,2-diphenyl-ethylenediamine-N,N′-di-3-propanoic acid - Crystal structure of H2-1,2-dpheddp•2HCl•H2O
    Radic, Gordana P.
    Glodovic, Verica V.
    Ratkovic, Zoran R.
    Novakovic, Sladana B.
    Garcia-Granda, Santiago
    Roces, Laura
    Menendez-Taboada, Laura
    Radojevic, Ivana D.
    Stefanovic, Olgica D.
    Comic, Ljiljana R.
    Trifunovic, Srecko R.
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1029 : 180 - 186
1234