Inkjet-printed energy storage device using graphene/polyaniline inks

被引:172
作者
Xu, Yanfei [1 ]
Hennig, Ingolf [2 ]
Freyberg, Dieter [3 ]
Strudwick, Andrew James [1 ]
Schwab, Matthias Georg [1 ]
Weitz, Thomas [3 ]
Cha, Kitty Chih-Pei [1 ]
机构
[1] BASF SE, GVM I, Carbon Mat Innovat Ctr, D-67056 Ludwigshafen, Germany
[2] BASF SE, GMC R, D-67056 Ludwigshafen, Germany
[3] BASF SE, GVE F, D-67056 Ludwigshafen, Germany
关键词
Graphene/polyaniline ink; Inkjet printing; Thin-film electrode; Supercapacitor; Industrial applicability; REDUCED GRAPHENE OXIDE; SUPERCAPACITOR; PAPER; POLYMER; HYBRID; SHEETS; CELLS;
D O I
10.1016/j.jpowsour.2013.09.096
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, graphene/polyaniline (NGP/PANI) inks are formulated; inkjet printing technology is then used to produce NGP/PANI thin-film electrodes from these inks. With this inkjet printing, good control over a number of key film properties including pattern geometry, pattern location, film thickness, and electrical conductivity is achieved. Two-electrode supercapacitors are fabricated using these thin-film electrodes. Electrochemical measurements with a 1 M H2SO4 electrolyte yield a maximum specific capacitance of 82 F g(-1), power density of 124 kW kg(-1) and energy density of 2.4 Wh kg(-1) when a scan rate of 20 mV s(-1) is applied. The supercapacitors show a long cycle life over 1000 cycles. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:483 / 488
页数:6
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