Polymerizations under electrochemical control

被引：29

作者：

Plamper, Felix A. ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Phys Chem, D-52056 Aachen, Germany

来源：

COLLOID AND POLYMER SCIENCE | 2014年 / 292卷 / 04期

关键词：

Polymer; ATRP; RAFT; Click; Electrochemical; polymerization; TRANSFER RADICAL POLYMERIZATION; ACID REDOX SYSTEMS; CONDUCTING POLYMERS; RAFT POLYMERIZATION; BLOCK-COPOLYMERS; CLICK CHEMISTRY; METHYL-CHLORIDE; HYDROGEL FILMS; ELECTROPOLYMERIZATION; ACRYLAMIDE;

D O I：

10.1007/s00396-014-3174-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The recent advances in polymerizations under electrochemical control are reviewed. Here, emphasis is laid not only on chain-growth polymerizations but also step-growth polymerizations and polymer modification are addressed. Relatedly, the latest developments in electrochemically controlled surface patterning are highlighted. In most cases, the scope of standard polymerization mechanisms was expanded by superimposing electrochemistry either at the start, during, or after polymerization. In contrast, electrode modification due to electropolymerizations (i.e., monomers are oxidized/reduced in order to form polymer films) is not the main topic of this minireview. Ring opening polymerizations under chemical redox control are shortly addressed. Future advances in this field are anticipated.

引用

页码：777 / 783

页数：7

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