μ-Terephthalato-bis[aquachloro(1,10-phenanthroline)copper(II)] μ-terephthalato-bis[diaqua(1,10-phenanthroline)cuprate(II)] dichloride dihydrate

被引：5

作者：

Chen, F ^{[1
]}

Li, XH ^{[1
]}

Xiao, HP ^{[1
]}

Hu, ML ^{[1
]}

机构：

[1] Wenshou Normal Coll, Dept Chem & Mat Sci, Wenzhou 325027, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804010086

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu2Cl2(C8H4O4)(C12H8N2)(2)(H2O)(2)].-[Cu-2(C8H4O4)(C12H8N2) (2)(H2O)(4)]Cl(2.)2H(2)O, each Cu atom has a distorted square-pyramidal geometry, but the coordination environments of the two independent Cu centres (Cu1 and Cu2) are very different. Atom Cu1 is surrounded by an O atom from a terephthalate dianion, an aqua O atom, a Cl atom and two N atoms from a 1,10-phenanthroline ligand. Atom Cu2 is surrounded by an O atom from a terephthalate dianion, two aqua O atoms and two N atoms from a 1,10-phenanthroline ligand. The terephthalate dianions, which function as bridges between the cationic and neutral complexes, lie on inversion centres.

引用

页码：M708 / M710

页数：3

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