Synthesis, Structure and Electrochemistry of [Ru2(S2CNMe2)3(μ3-S2CNMe2)2]2[Mo6O19]•2CH3COCH3

被引：3

作者：

Wu, Fang-Hui ^{[1
,2
]}

Liu, Yang-Li ^{[1
]}

Duan, Taike ^{[1
]}

Lu, Lude ^{[2
]}

Zhang, Qian-Feng ^{[1
]}

Leung, Wa-Hung ^{[3
]}

机构：

[1] Anhui Univ Technol, Inst Mol Engn & Appl Chem, Maanshan 243002, Anhui, Peoples R China

[2] Nanjing Univ Sci & Technol, Mat Chem Lab, Nanjing 210094, Peoples R China

[3] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2009年 / 64卷 / 07期

关键词：

Ruthenium; Dithiocarbamate; Hexamolybdate; Synthesis; Crystal Structure; Electrochemistry; CRYSTAL-STRUCTURE; COMPLEXES; CLUSTERS; CATION; HEXAMOLYBDATE; RUTHENIUM(II); OXIDATION; LIGAND; OXIDE; ION;

D O I：

10.1515/znb-2009-0704

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of MoO2(S2CNMe2)(2) with RUCl3 center dot xH(2)O in acetone at reflux afforded [RU2(S2CNMe2)(3)(mu(3)-S2CNMe2)(2)](2)[MO6O19]center dot 2CH(3)COCH(3) (1 center dot 2CH(3)COCH(3)) which was characterized by single-crystal X-ray diffraction to show a dinuclear ruthenium-dithiocarbamate species as cation and hexamolybdate as counter anion. The [Ru-2(S2CNMe2)(3)(mu(3)-S2CNMe2)(2)](+) cation may be considered as a combination of [Ru(S2CNMe2)(3)] with it cis-[Ru(S2CNMe2)(2)](+) species, and the Lindqvist anion [Mo6O19](2-) is located on an inversion center between two cations. Spectroscopic properties along with the electrochemistry of compound 1 center dot 2CH(3)COCH(3) are reported.

引用

页码：800 / 804

页数：5

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