Synthesis and characterisation of La1-xSrxCoO3 with large surface area

被引:57
作者
Berger, D
Fruth, V
Jitaru, I
Schoonman, J
机构
[1] Politeh Univ Bucharest, Dept Inorgan Chem, Bucharest 78126, Romania
[2] Delft Univ Technol, Inorgan Chem Lab, NL-2628 BL Delft, Netherlands
[3] Acad Romana, Inst Phys Chem, Bucharest 77208, Romania
关键词
perovskites; complex precursor; La(1-x)SrxCoO(3); nanomaterials; high surface area; powder technology;
D O I
10.1016/j.matlet.2004.02.035
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The paper presents a simple technique for synthesis of La1-xSrxCoO3 (v=0-0.3) nanopowders by calcining maleate-based precursors. The complex precursors were characterised by chemical analysis, electronic and FT-IR spectra and DTA-TG analysis. The XRD data for La1-xSrxCoO3 show that the samples are single phase with rhombohedral distorted perovskite structure. Specific surface area results of La1-xSrxCoO3 samples indicated values in the range 30-38 m(2)/g, which are high values for perovskite-type oxides. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2418 / 2422
页数:5
相关论文
共 14 条
  • [1] [Anonymous], 1984, INORGANIC ELECT SPEC
  • [2] Synthesis and characterization of nanophasic LaCoO3 powders
    Armelao, L
    Bandoli, G
    Barreca, D
    Bettinelli, M
    Bottaro, G
    Caneschi, A
    [J]. SURFACE AND INTERFACE ANALYSIS, 2002, 34 (01) : 112 - 115
  • [3] Solid state ceramic gas sensors based on interfacing ionic conductors with semiconducting oxides
    Di Bartolomeo, E
    Traversa, E
    Baroncini, M
    Kotzeva, V
    Kumar, RV
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (16) : 2691 - 2699
  • [4] Solubility of cerium in LaCoO3-influence on catalytic activity
    French, SA
    Catlow, CRA
    Oldman, RJ
    Rogers, SC
    Axon, SA
    [J]. CHEMICAL COMMUNICATIONS, 2002, (22) : 2706 - 2707
  • [5] Hwang HJ, 2000, J AM CERAM SOC, V83, P2852, DOI 10.1111/j.1151-2916.2000.tb01643.x
  • [6] Mixed electronic and ionic conductivity of LaCo(M)O3 (M = Ga, Cr, Fe or Ni) -: II.: Oxygen permeation through Cr- and Ni-substituted LaCoO3
    Kharton, VV
    Kovalevsky, AV
    Tikhonovich, VN
    Naumovich, EN
    Viskup, AP
    [J]. SOLID STATE IONICS, 1998, 110 (1-2) : 53 - 60
  • [7] Syntheses of perovskite-type composite oxides nanocrystals by solid-state reactions
    Li, F
    Zheng, HG
    Jia, DZ
    Xin, XQ
    Xue, ZL
    [J]. MATERIALS LETTERS, 2002, 53 (4-5) : 282 - 286
  • [8] Cathode materials for intermediate temperature SOFCs
    Maguire, E
    Gharbage, B
    Marques, FMB
    Labrincha, JA
    [J]. SOLID STATE IONICS, 2000, 127 (3-4) : 329 - 335
  • [9] The nature of active sites for the oxidation of methane on La-based perovskites
    Milt, VG
    Spretz, R
    Ulla, MA
    Lombardo, EA
    Fierro, JLG
    [J]. CATALYSIS LETTERS, 1996, 42 (1-2) : 57 - 63
  • [10] Nakamoto K., 2009, Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part A: Theory and Applications in Inorganic Chemistry, V6th ed.