Cadmium(II) and cobalt(II) coordination polymers constructed from 4,4′-di(1H-imidazol-4-yl)biphenyl and varied multicarboxylate ligands: Synthesis, structure and property

被引：15

作者：

Chen, Kai ^{[1
]}

Kang, Yan-Shang ^{[1
]}

Luo, Li ^{[1
]}

Zhao, Yue ^{[1
]}

Wang, Peng ^{[1
]}

Liu, Qing ^{[1
]}

Lu, Yi ^{[1
]}

Sun, Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem,Nanjing Natl Lab Mic, Nanjing 210093, Jiangsu, Peoples R China

来源：

POLYHEDRON | 2014年 / 79卷

基金：

中国国家自然科学基金;

关键词：

Cadmium(II) complex; Cobalt(II) complex; Luminescence; Sorption property; Coordination polymer; METAL-ORGANIC FRAMEWORKS; MIXED 1,3-DI(1H-IMIDAZOL-4-YL)BENZENE; COMPLEXES; NETWORKS; DICARBOXYLATE; SILVER(I); ANION;

D O I：

10.1016/j.poly.2014.05.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five new coordination polymers [Cd-2(H2L)(BPDA)(2)] (1), [Cd-2(HL)(H2L)(1.5)(BHTC)]center dot H2O (2), [Cd-2(H2L)(2) (BPTC)]center dot H2L (3), [CO2(HL)(2)(BPDA)] (4) and [Co-2(H2L)(2)(BPTC)]center dot 4H(2)O (5) have been isolated by reactions of corresponding metal salt with 4,4'-di(1H-imidazol-4-yl)biphenyl (H2L) and multicarboxylic acids of biphenyl-4,4'-dicarboxylic acid (H(2)BPDA), biphenyl-3,4',5-tricarboxylic acid (H3BHTC) and biphenyl-3,3',5,5'-tetracarboxylic acid (H4BPTC) and structurally characterized. 1 forms a 5-fold interpenetrating 3D dmp net by cross-linking of two different kinds of infinite zigzag chains of Cd-H2L and Cd-BPDA, 2 and 5 are 2D networks with different topologies, 3 is a 3D sqc11 net with Cd-BPTC layers pillared by H2L, while 4 exhibits a 3D InS net with Co-H2L 2D networks further connected by BPDA(2-) ligands. Thermal stability of the complexes, solid state luminescent property of 1-3 and sorption property of 5 have been investigated. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：239 / 249

页数：11

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