Conversion of hydrosilanes to silanols and silyl esters catalyzed by [Ph(3)PCuH](6)

被引：72

作者：

Schubert, U

Lorenz, C

机构：

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 06期

关键词：

D O I：

10.1021/ic961134+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ph(3)PCuH](6) is an efficient catalyst for the dehydrogenative coupling between the tertiary hydrosilanes Ph(3)SiH, Ph(2)MeSiH, Me(2)PhSiH, or Et(3)SiH and water or acetic acid to give silanols or silyl acetates.

引用

页码：1258 / +

页数：3

共 17 条

[1] POLYMERIZATION OF PRIMARY SILANES TO LINEAR POLYSILANES CATALYZED BY TITANOCENE DERIVATIVES [J].

AITKEN, C ;

HARROD, JF ;

SAMUEL, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 279 (1-2) :C11-C13

[2] PREPARATION OF ORGANOSILANOLS VIA METAL-CATALYZED REACTION OF ORGANOSILICON HYDRIDES WITH WATER [J].

BARNES, GH ;

DAUGHENB.NE .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (03) :885-&

[3] CONVERSION OF HYDROSILANES TO ALKOXYSILANES CATALYZED BY CP2TICL2/NORMAL-BULI [J].

BEDARD, TC ;

COREY, JY .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 428 (03) :315-333

[4] SIMPLIFIED, ONE-POT PROCEDURE FOR THE SYNTHESIS OF [(PH3P)CUH]6, A STABLE COPPER HYDRIDE FOR CONJUGATE REDUCTIONS [J].

BRESTENSKY, DM ;

HUSELAND, DE ;

MCGETTIGAN, C ;

STRYKER, JM .

TETRAHEDRON LETTERS, 1988, 29 (31) :3749-3752

[5] FORMATION OF SI-SI BONDS FROM SI-H BONDS IN THE PRESENCE OF HYDROSILATION CATALYSTS [J].

BROWNWENSLEY, KA .

ORGANOMETALLICS, 1987, 6 (07) :1590-1591

[6] New Route to Hybrid Materials: Rhodium Complex and Fluoride Ion Catalysed Hydrolysis of Hydrogenosilanes [J].

Corriu, Robert J. P. ;

Moreau, Joel J. E. ;

Man, Michel Wong Chi .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1994, 2 (1-3) :87-91

[7]

EGGER C, 1991, Z NATURFORSCH B, V46, P783

[8]

ETIENNE Y, 1952, CR HEBD ACAD SCI, V235, P966

[9] INTERACTION OF ALKOXYSILANES AND ACETOXYSILANES [J].

HAGGERTY, WJ ;

BREED, LW .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (07) :2464-&

[10]

HEPPER SP, 1974, J ORGANOMET CHEM, V80, pC21

← 1 2 →