Syntheses of thiopyrylium-tungsten complexes

被引：1

作者：

Garakaninezhad, Mona ^{[1
]}

Abedini, Mansour ^{[1
]}

Pirelahi, Hooshang ^{[1
]}

Amini, Mostafa M. ^{[2
]}

Mirzaei, Peiman ^{[2
]}

机构：

[1] Univ Tehran, Sch Chem, Univ Coll Sci, Tehran, Iran

[2] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran

来源：

TRANSITION METAL CHEMISTRY | 2009年 / 34卷 / 04期

关键词：

TROPYLIUM-METAL-COMPLEXES; CYCLOHEPTATRIENE;

D O I：

10.1007/s11243-009-9213-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hexacarbonyltungsten reacts with 2,4,6-triphenylthiopyrylium perchlorate and 2,6-dianisyl-4-phenylthiopyrylium perchlorate in diglyme to afford cationic thiopyrylium salts, 2,4,6-[H-2(C6H5)(3)C5SW(CO)(3)]+ClO4 (-) and 2,6,4-[H-2(C6H5)(C6H4OCH3)(2)C5SW(CO)(3)]+ClO4 (-). Both compounds were characterized by physico-chemical and spectroscopic methods. The HMQC, DEPT-45, and COSY experiments were used to assign carbon and proton signals in the H-1 and C-13 NMR spectra.

引用

页码：431 / 435

页数：5

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