Synthesis, structure and capacitive properties of cobalt hydroxide films on stainless steel substrates

被引:10
作者
Barauskiene, Ieva [1 ]
Valatka, Eugenijus [1 ]
机构
[1] Kaunas Univ Technol, Dept Phys & Inorgan Chem, LT-50254 Kaunas, Lithuania
来源
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2014年 / 12卷 / 11期
关键词
Cobalt hydroxide; Capacitance; Supercapacitors; Metal fibre filters; PERFORMANCE ELECTRODE MATERIAL; ELECTROCHEMICAL CAPACITANCE; OXIDE-FILMS; NICKEL; SUPERCAPACITORS; DEPOSITION; CO(OH)(2); ROUTE;
D O I
10.2478/s11532-014-0570-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cobalt (hydro)oxide films on AISI 304 stainless steel and sintered metal fibre filter Bekipor ST 20AL3 were prepared using electrochemical deposition from neutral cobalt acetate solutions under galvanostatic conditions. Deposited films were structurally characterized using X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy. All electrochemical measurements were performed in aqueous NaOH solution. Capacitive behavior of different films was evaluated using cyclic voltammetry data. The highest specific capacitance (965 F g(-1)) was reached when Bekipor ST 20AL3 mesh was used as a support for electroactive substance.
引用
收藏
页码:1206 / 1211
页数:6
相关论文
共 29 条
  • [1] Aahazadeh M., 2012, J APPL ELECTROCHEM, V42, P89
  • [2] Capacitance studies of cobalt compound nanowires prepared via electrodeposition
    Asano, Yosuke
    Komatsu, Toshiki
    Murashiro, Katsuyuki
    Hoshino, Katsuyoshi
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (11) : 5215 - 5222
  • [3] Nano-architectured Co(OH)2 electrodes constructed using an easily-manipulated electrochemical protocol for high-performance energy storage applications
    Chang, Jeng-Kuei
    Wu, Chih-Ming
    Sun, I-Wen
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (18) : 3729 - 3735
  • [4] Progress in electrical energy storage system: A critical review
    Chen, Haisheng
    Cong, Thang Ngoc
    Yang, Wei
    Tan, Chunqing
    Li, Yongliang
    Ding, Yulong
    [J]. PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2009, 19 (03) : 291 - 312
  • [5] Electrochemical Deposition of Porous Co(OH)2 Nanoflake Films on Stainless Steel Mesh for Flexible Supercapacitors
    Chou, Shu-Lei
    Wang, Jia-Zhao
    Liu, Hua-Kun
    Dou, Shi-Xue
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (12) : A926 - A929
  • [6] Homogeneous precipitation from solution by urea hydrolysis: A novel chemical route to the alpha-hydroxides of nickel and cobalt
    Dixit, M
    Subbanna, GN
    Kamath, PV
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (08) : 1429 - 1432
  • [7] Electrochemical capacitance of Co3O4 nanowire arrays supported on nickel foam
    Gao, Yinyi
    Chen, Shuli
    Cao, Dianxue
    Wang, Guiling
    Yin, Jinling
    [J]. JOURNAL OF POWER SOURCES, 2010, 195 (06) : 1757 - 1760
  • [8] Synthesis and electrochemical capacitive behaviors of Co3O4 nanostructures from a novel biotemplating technique
    Gong, Liangyu
    Liu, Xiaohong
    Su, Linghao
    Wang, Longqiang
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (01) : 297 - 304
  • [9] Potentiostatically deposited nanostructured α-Co(OH)2:: A high performance electrode material for redox-capacitors
    Gupta, Vinay
    Kusahara, Teruki
    Toyama, Hiroshi
    Gupta, Shubhra
    Miura, Norio
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (09) : 2315 - 2319
  • [10] Halper M.S., 2006, Supercapacitors: A brief overview