Highly active AuCo alloy nanoparticles encapsulated in the pores of metal-organic frameworks for hydrolytic dehydrogenation of ammonia borane

被引:116
作者
Li, Jun [1 ,2 ]
Zhu, Qi-Long [1 ]
Xu, Qiang [1 ,2 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Ikeda, Osaka, Japan
[2] Kobe Univ, Grad Sch Engn, Nada Ku, Kobe, Hyogo 657, Japan
关键词
CHEMICAL HYDROGEN STORAGE; POROUS COORDINATION POLYMER; PD NANOPARTICLES; NICKEL NANOPARTICLES; FORMIC-ACID; CATALYSIS; TEMPERATURE; SEPARATION; EFFICIENT; FUNCTIONALITY;
D O I
10.1039/c4cc00785a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrafine AuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 by using the double solvents method combined with the overwhelming reduction approach, which exert excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.
引用
收藏
页码:5899 / 5901
页数:3
相关论文
共 54 条
[1]   Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal-Organic Framework: A Double Solvents Approach [J].
Aijaz, Arshad ;
Karkamkar, Abhi ;
Choi, Young Joon ;
Tsumori, Nobuko ;
Roennebro, Ewa ;
Autrey, Tom ;
Shioyama, Hiroshi ;
Xu, Qiang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (34) :13926-13929
[2]   Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups [J].
Akiyama, George ;
Matsuda, Ryotaro ;
Sato, Hiroshi ;
Takata, Masaki ;
Kitagawa, Susumu .
ADVANCED MATERIALS, 2011, 23 (29) :3294-+
[3]   A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane [J].
Chandra, Manish ;
Xu, Qiang .
JOURNAL OF POWER SOURCES, 2006, 156 (02) :190-194
[4]   Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules [J].
Chen, Banglin ;
Xiang, Shengchang ;
Qian, Guodong .
ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1115-1124
[5]   Catalysis by metal nanoparticles embedded on metal-organic frameworks [J].
Dhakshinamoorthy, Amarajothi ;
Garcia, Hermenegildo .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (15) :5262-5284
[6]   Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].
Eddaoudi, M ;
Kim, J ;
Rosi, N ;
Vodak, D ;
Wachter, J ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2002, 295 (5554) :469-472
[7]   A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F ;
Dutour, J ;
Surblé, S ;
Margiolaki, I .
SCIENCE, 2005, 309 (5743) :2040-2042
[8]   Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences [J].
Ferey, Gerard ;
Serre, Christian .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1380-1399
[9]   A dynamic, isocyanurate-functionalized porous coordination polymer [J].
Ghosh, Sujit K. ;
Bureekaew, Sareeya ;
Kitagawa, Susumu .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) :3403-3406
[10]   Synergistic Catalysis of Metal-Organic Framework-Immobilized Au-Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage [J].
Gu, Xiaojun ;
Lu, Zhang-Hui ;
Jiang, Hai-Long ;
Akita, Tomoki ;
Xu, Qiang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (31) :11822-11825