E-Z isomerization of the -C=N- bond in anthracene-based acylhydrazone derivatives under visible light

被引:26
作者
Bai, Binglian [1 ,2 ]
Zhang, Mingang [2 ]
Ji, Nan [2 ]
Wei, Jue [2 ]
Wang, Haitao [1 ]
Li, Min [1 ]
机构
[1] Jilin Univ, Key Lab Automobile Mat JLU, Minist Educ, Changchun 130012, Peoples R China
[2] Jilin Univ, Coll Phys, Changchun 130012, Peoples R China
关键词
EMISSION ENHANCEMENT; PHOTO; ORGANOGEL; PHOTODIMERIZATION; DYNAMICS; STILBENE; GELATION;
D O I
10.1039/c6cc08403f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photoresponsive behaviour of AHP-mB8 upon irradiation by visible light was demonstrated to be due to the E-Z isomerizations of the -C=N- group, rather than the photodimerization of anthracene groups. In addition, the Z-isomer of AHP-mB8 was stable at room temperature. AHP-mB8 organogels showed visible light induced gel-sol transition and its mechanism was proposed.
引用
收藏
页码:2693 / 2696
页数:4
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