Bis(tetraorganodistannoxanes) as Secondary Building Block Units (SBUs) for the Generation of Porous Materials - A Three-Dimensional Honeycomb Architecture Containing Adamantane-type Water Clusters

被引：36
作者：
Garcia-Zarracino, Reyes [2 ]
Hopfl, Herbert [1 ]
Guizado-Rodriguez, Marisol [3 ]
机构：
[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62209, Morelos, Mexico
[2] Univ Autonoma Carmen, Fac Quim, Ciudad Del Carmen 24180, Mexico
[3] Univ Autonoma Estado Morelos, Ctr Invest Ingn & Ciencias Aplicadas, Cuernavaca 62209, Morelos, Mexico
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 04期
关键词：
SOLID-STATE STRUCTURES; CRYSTAL-STRUCTURE; DOUBLE LADDER; (H2O)(10) CLUSTER; COMPLEXES; ACID; POLYMERS; NETWORK; TETRAORGANODISTANNOXANE; CARBOXYLATES;
D O I：
10.1021/cg801313u
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The metal-directed self-assembly of dimethyltin(IV) and homophthalate provided tetranuclear bis(tetraorganodistannoxane) secondary building units (SBUs), which in the solid state are linked to a three-dimensional honeycomb architecture having hexameric channels with diameters of 5.2 angstrom. These channels are occupied by water clusters of composition (H2O)(x) (with x = 12-14) that have adamantane-type structures as they are found in the cubic ice modification.
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页码：1651 / 1654
页数：4
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