Studies on Sodium Ion Conducting Gel Polymer Electrolytes

被引：11
|
作者：
Isa, Khairul Bahiyah Md [1 ]
Othman, Lisani [1 ]
Zainol, Nurul Husna [1 ]
Samin, Siti Mariam [1 ]
Gie, Chong Woon [1 ]
Osman, Zurina [1 ]
Arof, Abdul Kariem Mohd [2 ]
机构：
[1] Univ Malaya, Dept Phys, Kuala Lumpur 50603, Malaysia
[2] Univ Malaya, Ctr Ionics, Kuala Lumpur 50603, Malaysia
来源：
ADVANCED MATERIALS ENGINEERING AND TECHNOLOGY II | 2014年 / 594-595卷
关键词：
Gel polymer electrolytes; PVdF-HFP; sodium triflate; conductivity; TGA; DISCHARGE CHARACTERISTICS; LITHIUM BATTERIES; TRANSPORT; MEMBRANE; IMPEDANCE; GLASSES;
D O I：
10.4028/www.scientific.net/KEM.594-595.786
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Sodium ion conducting gel polymer electrolyte (GPE) films consisting of polyvinylidenefluoride-co-hexafluoropropylene (PVdF-HFP) as a polymer host were prepared using the solution casting technique. Sodium trifluoromethane-sulfonate (NaCF3SO3) was used as an ionic salt and the mixture of ethylene carbonate (EC) and propylene carbonate (PC) as the solvent plasticizer. The GPE films were found to be stable up to temperature of 145 degrees C as shown by TGA analysis. The AC impedance study show that the optimum conductivity of 2.50 x 10(-3) S cm(-1) at room temperature is achieved for the film containing 20 wt.% of NaCF3SO3 salt. The temperature dependence of conductivity obeys VTF relation in the temperature range of 303 K to 373 K.
引用
收藏
页码：786 / +
页数：2
相关论文
共 50 条
  • [31] Proton conducting Gel Polymer Electrolytes for supercapacitor applications
    Latoszynska, Anna A.
    Taberna, Pierre-Louis
    Simon, Patrice
    Wieczorek, Wladyslaw
    ELECTROCHIMICA ACTA, 2017, 242 : 31 - 37
  • [32] Synthesis, electrochemical and optical studies of poly(ethylene oxide) based gel-polymer electrolytes for sodium-ion secondary batteries
    Menisha, M.
    Senavirathna, S. L. N.
    Vignarooban, K.
    Iqbal, N.
    Pitawala, H. M. J. C.
    Kannan, A. M.
    SOLID STATE IONICS, 2021, 371
  • [33] Hierarchical Nanocellulose-Based Gel Polymer Electrolytes for Stable Na Electrodeposition in Sodium Ion Batteries
    Mittal, Neeru
    Tien, Sean
    Lizundia, Erlantz
    Niederberger, Markus
    SMALL, 2022, 18 (43)
  • [34] Immobilized cation functional gel polymer electrolytes with high lithium transference number for lithium ion batteries
    Tsao, Chih-Hao
    Su, Hou-Ming
    Huang, Hsiang-Ting
    Kuo, Ping-Lin
    Teng, Hsisheng
    JOURNAL OF MEMBRANE SCIENCE, 2019, 572 : 382 - 389
  • [35] The effects of solvents on the physical and electrochemical properties of potassium-ion conducting polymer gel electrolytes
    Madhani, Vaishali
    Rathore, Mahendra Singh
    Kumar, Deepak
    HIGH PERFORMANCE POLYMERS, 2023, 35 (01) : 28 - 35
  • [36] Electrochemical and Mechanical Properties of Sodium-Ion Conducting Cross-Linked Polymer Gel Electrolyte
    Xue, Yuan
    Li, Xiang
    Quesnel, David J.
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2017, 12 (11): : 10674 - 10686
  • [37] Gel Polymer Electrolytes in Lithium Batteries
    Yang, Qi
    Deng, Nanping
    Cheng, Bowen
    Kang, Weimin
    PROGRESS IN CHEMISTRY, 2021, 33 (12) : 2270 - 2282
  • [38] Sodium ion conducting gel polymer electrolyte using poly(vinylidene fluoride hexafluoropropylene)
    Duy Thanh Vo
    Hoang Nguyen Do
    Thien Trung Nguyen
    Thi Tuyet Hanh Nguyen
    Van Man Tran
    Okada, Shigeto
    My Loan Phung Le
    MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2019, 241 : 27 - 35
  • [39] Electrical and electrochemical studies on magnesium ion-based polymer gel electrolytes
    S. K. Tripathi
    Amrita Jain
    Ashish Gupta
    Manju Mishra
    Journal of Solid State Electrochemistry, 2012, 16 : 1799 - 1806
  • [40] A comparative study of lithium and sodium salts in PAN-based ion conducting polymer electrolytes
    Zurina Osman
    Khairul Bahiyah Md Isa
    Azhar Ahmad
    Lisani Othman
    Ionics, 2010, 16 : 431 - 435
12345