Studies on Sodium Ion Conducting Gel Polymer Electrolytes

被引：11

作者：

Isa, Khairul Bahiyah Md ^{[1
]}

Othman, Lisani ^{[1
]}

Zainol, Nurul Husna ^{[1
]}

Samin, Siti Mariam ^{[1
]}

Gie, Chong Woon ^{[1
]}

Osman, Zurina ^{[1
]}

Arof, Abdul Kariem Mohd ^{[2
]}

机构：

[1] Univ Malaya, Dept Phys, Kuala Lumpur 50603, Malaysia

[2] Univ Malaya, Ctr Ionics, Kuala Lumpur 50603, Malaysia

来源：

ADVANCED MATERIALS ENGINEERING AND TECHNOLOGY II | 2014年 / 594-595卷

关键词：

Gel polymer electrolytes; PVdF-HFP; sodium triflate; conductivity; TGA; DISCHARGE CHARACTERISTICS; LITHIUM BATTERIES; TRANSPORT; MEMBRANE; IMPEDANCE; GLASSES;

D O I：

10.4028/www.scientific.net/KEM.594-595.786

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Sodium ion conducting gel polymer electrolyte (GPE) films consisting of polyvinylidenefluoride-co-hexafluoropropylene (PVdF-HFP) as a polymer host were prepared using the solution casting technique. Sodium trifluoromethane-sulfonate (NaCF3SO3) was used as an ionic salt and the mixture of ethylene carbonate (EC) and propylene carbonate (PC) as the solvent plasticizer. The GPE films were found to be stable up to temperature of 145 degrees C as shown by TGA analysis. The AC impedance study show that the optimum conductivity of 2.50 x 10(-3) S cm(-1) at room temperature is achieved for the film containing 20 wt.% of NaCF3SO3 salt. The temperature dependence of conductivity obeys VTF relation in the temperature range of 303 K to 373 K.

引用

页码：786 / +

页数：2

共 50 条

[21] Novel zinc ion conducting polymer gel electrolytes based on ionic liquids
Xu, JJ
Ye, H
Huang, J
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (12) : 1309 - 1317
[22] Sol-gel derived Li-ion conducting polymer electrolytes
Zelazowska, E
Rysiakiewicz-Pasek, E
Borczuch-Laczka, M
MATERIALS SCIENCE-POLAND, 2005, 23 (01): : 177 - 194
[23] Electrical and electrochemical properties of magnesium ion conducting composite gel polymer electrolytes
Pandey, G. P.
Agrawal, R. C.
Hashmi, S. A.
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2010, 43 (25)
[24] Li Ion Conducting Gel Polymer Electrolytes Based on Poly(vinyl acetate)
Rajendran, S.
Mathew, Chithra M.
Marimuthu, T.
Kesavan, K.
PROCEEDING OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN APPLIED PHYSICS & MATERIAL SCIENCE (RAM 2013), 2013, 1536 : 775 - 776
[25] Application of Single-Ion Conducting Gel Polymer Electrolytes in Magnesium Batteries
Merrill, Laura C.
Ford, Hunter O.
Schaefer, Jennifer L.
ACS APPLIED ENERGY MATERIALS, 2019, 2 (09) : 6355 - 6363
[26] ION-CONDUCTING POLYMER ELECTROLYTES
SCROSATI, B
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1989, 59 (01): : 151 - 160
[27] Synthesis and electrochemical study of sodium ion transport polymer gel electrolytes
Xue, Yuan
Quesnel, David J.
RSC ADVANCES, 2016, 6 (09): : 7504 - 7510
[28] Ion-conducting polymer electrolytes
Scrosati, Bruno
Philosophical Magazine B: Physics of Condensed Matter; Electronic, Optical and Magnetic Properties, 1989, 59 (01): : 151 - 160
[29] CuInS2 Nanospheres and Nanowhiskers Enhancing the Electrochemical Properties of Sodium-Ion-Conducting Gel Polymer Electrolytes
Giri, Ranjan Kr.
Patel, Maitri
Kumar, Deepak
Hmar, Jehova Jire L.
Chaki, Sunil H.
Deshpande, Milind P.
Kanchan, Dinesh Kumar
ACS APPLIED NANO MATERIALS, 2024, 7 (03) : 2855 - 2866
[30] Effect of introducing different molecular liquid solvents on electrochemical and physical properties of sodium ion conducting polymer gel electrolytes
Patel, Maitri
Chaudhary, N. A.
Kumar, Deepak
Mishra, Kuldeep
Das, Neeladri
Prajapati, A. N.
JOURNAL OF MOLECULAR LIQUIDS, 2024, 410

← 1 2 3 4 5 →