Studies on Sodium Ion Conducting Gel Polymer Electrolytes

被引:11
|
作者
Isa, Khairul Bahiyah Md [1 ]
Othman, Lisani [1 ]
Zainol, Nurul Husna [1 ]
Samin, Siti Mariam [1 ]
Gie, Chong Woon [1 ]
Osman, Zurina [1 ]
Arof, Abdul Kariem Mohd [2 ]
机构
[1] Univ Malaya, Dept Phys, Kuala Lumpur 50603, Malaysia
[2] Univ Malaya, Ctr Ionics, Kuala Lumpur 50603, Malaysia
关键词
Gel polymer electrolytes; PVdF-HFP; sodium triflate; conductivity; TGA; DISCHARGE CHARACTERISTICS; LITHIUM BATTERIES; TRANSPORT; MEMBRANE; IMPEDANCE; GLASSES;
D O I
10.4028/www.scientific.net/KEM.594-595.786
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sodium ion conducting gel polymer electrolyte (GPE) films consisting of polyvinylidenefluoride-co-hexafluoropropylene (PVdF-HFP) as a polymer host were prepared using the solution casting technique. Sodium trifluoromethane-sulfonate (NaCF3SO3) was used as an ionic salt and the mixture of ethylene carbonate (EC) and propylene carbonate (PC) as the solvent plasticizer. The GPE films were found to be stable up to temperature of 145 degrees C as shown by TGA analysis. The AC impedance study show that the optimum conductivity of 2.50 x 10(-3) S cm(-1) at room temperature is achieved for the film containing 20 wt.% of NaCF3SO3 salt. The temperature dependence of conductivity obeys VTF relation in the temperature range of 303 K to 373 K.
引用
收藏
页码:786 / +
页数:2
相关论文
共 50 条
  • [1] Ion Transport in Solvated Sodium-Ion Conducting Gel Polymer Electrolytes
    Kuray, Preeya
    Mei, Wenwen
    Sheffield, Sarah E.
    Sengeh, Joseph
    Pulido, Carlos Rolando Fernandez
    Capparelli, Clara
    Hickey, Robert J.
    Hickner, Michael A.
    FRONTIERS IN ENERGY RESEARCH, 2020, 8
  • [2] Ionic liquid based sodium ion conducting gel polymer electrolytes
    Kumar, Deepak
    Hashmi, S. A.
    SOLID STATE IONICS, 2010, 181 (8-10) : 416 - 423
  • [3] Sodium-ion conducting polymer electrolytes
    Zhi-Yong Li
    Zhuo Li
    Jia-Long Fu
    Xin Guo
    Rare Metals, 2023, 42 : 1 - 16
  • [4] Sodium-ion conducting polymer electrolytes
    Zhi-Yong Li
    Zhuo Li
    Jia-Long Fu
    Xin Guo
    Rare Metals, 2023, 42 (01) : 1 - 16
  • [5] Sodium-ion conducting polymer electrolytes
    Li, Zhi-Yong
    Li, Zhuo
    Fu, Jia-Long
    Guo, Xin
    RARE METALS, 2023, 42 (01) : 1 - 16
  • [6] Structural, electrical and electrochemical studies of sodium ion conducting blend polymer electrolytes
    Gupta, Ashish
    Jain, Amrita
    Kumari, Manju
    Tripathi, S. K.
    MATERIALS TODAY-PROCEEDINGS, 2021, 34 : 780 - 786
  • [7] A sodium ion conducting gel polymer electrolyte
    Yang, Y. Q.
    Chang, Z.
    Li, M. X.
    Wang, X. W.
    Wu, Y. P.
    SOLID STATE IONICS, 2015, 269 : 1 - 7
  • [8] FTIR studies on proton conducting polymer gel electrolytes
    Sekhon, SS
    Singh, HP
    SOLID STATE IONICS: THE SCIENCE AND TECHNOLOGY OF IONS IN MOTION, 2004, : 1033 - 1040
  • [9] Electrical and Electrochemical Studies on Sodium Ion-based Gel Polymer Electrolytes
    Isa, K. B. Md
    Othman, L.
    Hambali, D.
    Osman, Z.
    4TH INTERNATIONAL CONFERENCE ON THE ADVANCEMENT OF MATERIALS AND NANOTECHNOLOGY (ICAMN IV 2016), 2017, 1877
  • [10] Synthesis and electrochemical studies on sodium ion conducting PVP based solid polymer electrolytes
    Vahini, M.
    Muthuvinayagam, M.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (06) : 5609 - 5619