Trapped Molecular and Ionic Species in Poled Borosilicate Glasses: Toward a Rationalized Description of Thermal Poling in Glasses

被引：34

作者：

Cremoux, Tatiana ^{[1
]}

Dussauze, Marc ^{[1
]}

Fargin, Evelyne ^{[2
]}

Cardinal, Thierry ^{[2
]}

Talaga, David ^{[1
]}

Adamietz, Frederic ^{[1
]}

Rodriguez, Vincent ^{[1
]}

机构：

[1] Univ Bordeaux, Inst Sci Mol, CNRS, UMR 5255, F-33400 Talence, France

[2] Univ Bordeaux, ICMCB, CNRS, UPR 9048, F-33600 Pessac, France

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2014年 / 118卷 / 07期

关键词：

HIGH 2ND-ORDER NONLINEARITIES; MASS-SPECTROMETRY; NITROGEN-DIOXIDE; GLOW-DISCHARGES; BORATE GLASSES; RAMAN; TEMPERATURE; SPECTRA; POLARIZATION; SPECTROSCOPY;

D O I：

10.1021/jp4101015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular and ionic species of nitrogen oxides have been injected, formed, and then trapped within a borosilicate glass during a thermal poling process. This original observation denotes a new aspect of poling mechanisms for ionic glasses. For each poled borosilicate glasses studied, compositional, structural, and second harmonic generation profiles of their subanodic polarized layers have been characterized. A description of the space charge implementation process, involving interactions between charged and chemically active species formed both within plasma discharges at the glass/electrode interface and within the polarized glass matrix, is proposed.

引用

页码：3716 / 3723

页数：8

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