One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

被引：19

作者：

Gungor, Fusun Seyma ^{[1
]}

Kiskan, Bans ^{[1
]}

机构：

[1] Istanbul Tech Univ, Fac Sci & Letters, Dept Chem, TR-34469 Istanbul, Turkey

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2014年 / 75卷

关键词：

One-pot synthesis; Click chemistry; Polytriazole; Poly(epsilon-caprolactone); Graft copolymer; THIOL-YNE CHEMISTRY; EPSILON-CAPROLACTONE; ORTHOGONAL SYNTHESIS; MATERIALS SCIENCE; ENE; COMBINATION; POLYMERS; POLYLACTONES; EFFICIENT; KINETICS;

D O I：

10.1016/j.reactfunctpolym.2013.12.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The one-pot construction of polytriazole grafted with poly(epsilon-caprolactone) via the polymerization of 4-azido-1-(prop-2-yn-1-yloxy)butan-2-ol (N(3)hydroxypropargyl) and epsilon-caprolactone monomers is reported. For this purpose, a click reaction and ring-opening polymerization (ROP) were combined and carried out simultaneously. N(3)hydroxypropargyl served as both the ROP initiator and a monomer for the click polymerization. Thus, an in situ "grafting-through and from" strategy was established in one pot. CuBr and Sn(Oct)(2) were utilized as dual catalysts, and the polymerization reactions were carried out at 120 degrees C under a N-2 atmosphere. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：51 / 55

页数：5

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