Synthesis and electrochemical behavior of layered Li(Ni0.5-xCo2xMn0.5-x)O2 (x=0 and 0.025) materials prepared by solid-state reaction method

被引:24
作者
Sun, YK [1 ]
Kang, SH
Amine, K
机构
[1] Hanyang Univ, Ctr Informat & Commun Mat, Dept Chem Engn, Seoul 133791, South Korea
[2] Argonne Natl Lab, Electrochem Technol Program, Div Chem Engn, Argonne, IL 60439 USA
关键词
D O I
10.1016/j.materresbull.2004.02.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Layered Li(Ni0.5-xCO2xMn0.5-x)O-2 (x = 0 and 0.025) materials were prepared by conventional solid state reaction method combined with high energy ball milling (HEBM). The Li(Ni0.5-xCO2xMn0.5-x)O-2 electrodes delivered discharge capacity of 142-185 mAh/g depending on upper cut-off voltage limit with excellent cycleability. The charge/discharge and differential capacity versus voltage studies show that only one phase reaction occurs and no phase transition takes place during the electrochemical cycling. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:819 / 825
页数:7
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