cis-Dichloro[tris(diphenylphosphino-ethyl)amine]ruthenium(II)-chloroform-water (1/2.5/1)

被引:5
作者
Anzellotti, A
Briceño, A
Delgado, G
del Delgado, GD
Fontal, B
机构
[1] Inst Venezolano Invest Cient, Ctr Quim, Caracas 1020A, Venezuela
[2] Univ Los Andes, Fac Ciencias, Dept Quim, Merida 5101, Venezuela
关键词
D O I
10.1107/S0108270102008004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, [RuCl2(C42H42NP3)] ·2.5CHCl3·H2O, the Ru atom is six-coordinated, to one tetradentate tris(diphenylphosphinoethyl)amine ligand and two Cl atoms, in a distorted octahedral arrangement. Molecules of chloroform and water stabilize the framework through intermolecular hydrogen bonds.
引用
收藏
页码:M355 / M357
页数:3
相关论文
共 16 条
[1]   CIS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) AND TRANS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) COMPLEXES (RUX2(DMSO)4, X = CL, BR) - SYNTHESIS, STRUCTURE, AND ANTITUMOR-ACTIVITY [J].
ALESSIO, E ;
MESTRONI, G ;
NARDIN, G ;
ATTIA, WM ;
CALLIGARIS, M ;
SAVA, G ;
ZORZET, S .
INORGANIC CHEMISTRY, 1988, 27 (23) :4099-4106
[2]   ORTHORHOMBIC MODIFICATION OF DICHLOROTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) [J].
ATTIA, WM ;
CALLIGARIS, M .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :1426-1427
[3]   PALLADIUM COMPLEXES WITH THE TRIPODAL PHOSPHINE TRIS-(2-DIPHENYLPHOSPHINOETHYL)AMINE - SYNTHESIS AND STRUCTURE OF TRIGONAL, TETRAHEDRAL, TRIGONAL BIPYRAMIDAL, AND SQUARE-PLANAR COMPLEXES [J].
CECCONI, F ;
GHILARDI, CA ;
MIDOLLINI, S ;
MONETI, S ;
ORLANDINI, A ;
SCAPACCI, G .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (02) :211-216
[4]   OLIGOPHOSPHANE LIGANDS .32. CATALYTIC DIMERIZATION OF 1-ALKYNES TO LINEAR 1-EN-3-YNES ON CIS-ARYLHYDRIDORUTHENIUM(II) CHELATE COMPLEXES - MOLECULAR-STRUCTURE OF (PP3)RUH(C6H4CF3-3) (PP3=P(CH2CH2CH2PME2)3) [J].
DAHLENBURG, L ;
FROSIN, KM ;
KERSTAN, S ;
WERNER, D .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 407 (01) :115-124
[5]  
GHILARDI CA, 1975, CRYST STRUCT COMMUN
[6]   Modeling hydroxyl and water H atoms [J].
Nardelli, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :563-571
[7]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[8]   LOW- AND HIGH-SPIN 5-COORDINATE COBALT(2) AND NICKEL(2) COMPLEXES WITH TRIS(2-DIPHENYLPHOSPHINOETHYL)AMINE (NP3) [J].
SACCONI, L ;
BERTINI, I .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (20) :5443-&
[9]  
Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination
[10]  
*SIEM AN XRAY INST, 1994, SHELXTL REL 5 03