Synthesis of Ph2LSn(μ-OH)Bu3SnCl. Trapping of monomeric triorganotin hydroxide Ph2LSnOH

被引：7

作者：

Dostal, Libor ^{[1
]}

Taraba, Jan ^{[2
]}

Jambor, Roman ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic

[2] Masaryk Univ, Fac Sci, Dept Inorgan Chem, CZ-61137 Brno, Czech Republic

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 9-10期

关键词：

Organotin compounds; Pincer ligands; NMR spectroscopy; Crystal structure; SN-119; NMR-SPECTRA; C-13; TRANSESTERIFICATION; 4-COORDINATE; DERIVATIVES; CRYSTAL; ACIDS;

D O I：

10.1016/j.jorganchem.2009.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of triorganotin(IV) compound Ph2LSnCl (1), (L=2,6-(t-BuOCH2)(2)C6H3), with (Bu3Sn)(2)O resulted to the isolation of Ph2LSn(mu-OH)Bu3SnCl (2), in which a monomeric triorganotin(IV) hydroxide Ph2LSnOH intermolecularly coordinates Bu3SnCl moiety. Compound 2 was characterized by combination of H-1, C-13 and Sn-119 NMR spectroscopy, ESI/MS, elemental analysis and X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1251 / 1253

页数：3

共 50 条

[31] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF TRANS-IR(PR(3))2(CO)(NHR'), WHERE R=ME AND ET AND R'=PH AND BU(T)
RAHIM, M
BUSHWELLER, CH
AHMED, KJ
ORGANOMETALLICS, 1994, 13 (12) : 4952 - 4958
[32] [(Ph)3PBr][Br7], [(Bz)(Ph)3P]2[Br8], [(n-Bu)3MeN]2[Br20], [C4MPyr]2[Br20], and [(Ph)3PCl]2[Cl2l14]: Extending the Horizon of Polyhalides via Synthesis in Ionic Liquids
Wolff, Michael
Okrut, Alexander
Feldmann, Claus
INORGANIC CHEMISTRY, 2011, 50 (22) : 11683 - 11694
[33] Synthesis and Structure of Bismuth Complexes [Ph3(n-Pr)P]2+[Bi2I8•2Me2S=O]2-, [Ph3(iso-Bu)P]2+[Bi2I8•2Me2S=O]2-, [Ph3(n-Bu)P]2+[Bi2I8•2Me2S=O]2-, and [Ph3(n-Am)P]2+[Bi2I8•2Me2S=O]2-
Sharutin, V. V.
Egorova, I. V.
Klepikov, N. N.
Boyarkina, E. A.
Sharutina, O. K.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (02) : 239 - 247
[34] Synthesis and structure of bismuth complexes [Ph3(n-Pr)P]2+[Bi2I8 · 2Me2S=O]2−, [Ph3(iso-Bu)P]2+[Bi2I8 · 2Me2S=O]2−, [Ph3(n-Bu)P]2+[Bi2I8 · 2Me2S=O] 2−, and [Ph3(n-Am)P]2+[Bi2I8 · 2Me2S=O]2−
V. V. Sharutin
I. V. Egorova
N. N. Klepikov
E. A. Boyarkina
O. K. Sharutina
Russian Journal of Inorganic Chemistry, 2009, 54 : 239 - 247
[35] Synthesis and structure of gold and copper complexes: [Ph3PhCH2P]+[AuCl4]−, [NH(C2H4OH)3]+[AuCl4]− · H2O, and [Ph3EtP]2+[Cu2Cl6]2−
V. V. Sharutin
V. S. Senchurin
O. K. Sharutina
A. P. Pakusina
O. A. Fastovets
Russian Journal of Inorganic Chemistry, 2010, 55 : 1415 - 1420
[36] Synthesis, protonation and electrochemical properties of trinuclear NiFe2 complexes Fe2(CO)6(μ3-S)2[Ni(Ph2PCH2)2NR] (R = n-Bu, Ph) with an internal pendant nitrogen base as a proton relay
Duan, Lele
Wang, Mei
Li, Ping
Wang, Ning
Wang, Fujun
Sun, Licheng
INORGANICA CHIMICA ACTA, 2009, 362 (02) : 372 - 376
[37] Synthesis and reactivity of the monomeric late-transition-metal parent amido complex [Ir(Cp*)(PMe3)(Ph)(NH2)]
Rais, D
Bergman, RG
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (16) : 3970 - 3978
[38] Synthesis and structural characterization of new ladder-like organostannoxanes derived from carboxylic acid derivatives: [C5H4N(p-CO2)]2[Bu2Sn]4(μ3-O)2(μ2-OH)2, [Ph2CHCO2]4[Bu2Sn]4(μ3-O)2, and [(p-NH2)-C6H4-CO2]2[Bu2Sn]4(μ3-O)2(μ2-OH)2
Diop, Tidiane
Diop, Mouhamadou Birame
Diop, Cheikh Abdoul Khadir
Diasse-Sarr, Aminata
Sidibe, Mamadou
Dumitru, Florina
van der Lee, Arie
MAIN GROUP METAL CHEMISTRY, 2022, 45 (01) : 35 - 43
[39] SnPh3OH center dot Ph3AsO center dot H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
Sow, Yaya
Okio, Ariman Yavi Kochikpa
Diop, Libasse
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY, 2014, 15 (02): : 181 - 184
[40] Synthesis and reactivity of [Pd2L2R2(mu-OH)(2)]-type complexes (L = PEt3 or PPh3; R = Me, PhCH2 or Ph). Crystal structure of [Pd-2(PPh3)(2)Ph-2(mu-OH)(mu-NHC6H4OMe-p)]
Ruiz, J
Rodriguez, V
Lopez, G
Chaloner, PA
Hitchcock, PB
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22): : 4271 - 4276

← 1 2 3 4 5 →