Synthesis of Ph2LSn(μ-OH)Bu3SnCl. Trapping of monomeric triorganotin hydroxide Ph2LSnOH

被引：7

作者：

Dostal, Libor ^{[1
]}

Taraba, Jan ^{[2
]}

Jambor, Roman ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic

[2] Masaryk Univ, Fac Sci, Dept Inorgan Chem, CZ-61137 Brno, Czech Republic

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 9-10期

关键词：

Organotin compounds; Pincer ligands; NMR spectroscopy; Crystal structure; SN-119; NMR-SPECTRA; C-13; TRANSESTERIFICATION; 4-COORDINATE; DERIVATIVES; CRYSTAL; ACIDS;

D O I：

10.1016/j.jorganchem.2009.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of triorganotin(IV) compound Ph2LSnCl (1), (L=2,6-(t-BuOCH2)(2)C6H3), with (Bu3Sn)(2)O resulted to the isolation of Ph2LSn(mu-OH)Bu3SnCl (2), in which a monomeric triorganotin(IV) hydroxide Ph2LSnOH intermolecularly coordinates Bu3SnCl moiety. Compound 2 was characterized by combination of H-1, C-13 and Sn-119 NMR spectroscopy, ESI/MS, elemental analysis and X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1251 / 1253

页数：3

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