Synthesis of Ph2LSn(μ-OH)Bu3SnCl. Trapping of monomeric triorganotin hydroxide Ph2LSnOH

被引：7

作者：

Dostal, Libor ^{[1
]}

Taraba, Jan ^{[2
]}

Jambor, Roman ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, CZ-53210 Pardubice, Czech Republic

[2] Masaryk Univ, Fac Sci, Dept Inorgan Chem, CZ-61137 Brno, Czech Republic

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 9-10期

关键词：

Organotin compounds; Pincer ligands; NMR spectroscopy; Crystal structure; SN-119; NMR-SPECTRA; C-13; TRANSESTERIFICATION; 4-COORDINATE; DERIVATIVES; CRYSTAL; ACIDS;

D O I：

10.1016/j.jorganchem.2009.01.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of triorganotin(IV) compound Ph2LSnCl (1), (L=2,6-(t-BuOCH2)(2)C6H3), with (Bu3Sn)(2)O resulted to the isolation of Ph2LSn(mu-OH)Bu3SnCl (2), in which a monomeric triorganotin(IV) hydroxide Ph2LSnOH intermolecularly coordinates Bu3SnCl moiety. Compound 2 was characterized by combination of H-1, C-13 and Sn-119 NMR spectroscopy, ESI/MS, elemental analysis and X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：1251 / 1253

页数：3

共 50 条

[11] PRIMARY AMIDO AND AMINE ADDUCT COMPLEXES OF GALLIUM - SYNTHESIS AND STRUCTURES OF [TERT-BU2GA(MU-NHPH)]2 AND TERT-BU3GA.NH2PH
ATWOOD, DA
JONES, RA
COWLEY, AH
BOTT, SG
ATWOOD, JL
POLYHEDRON, 1991, 10 (16) : 1897 - 1902
[12] Synthesis and Crystal Structure of a Novel Mercapto-organotin Complex: [Et3NH] [Ph2SnCl（μ2-SCH2COO-）]
Xue Qing SONG
Qing Lan XIE
Xiao Niu FANG(Institute of Elemento-organic Chemistry
ChineseChemicalLetters, 1998, (10) : 977 - 978
[13] Synthesis and crystal structure of binuclear organotin (IV) complexes [Ph3Sn(CH3OH)O2CC6H4CO2(CH3OH)SnPh3]•2CH3OH and [Ph3SnS2CN(CH2CH2)2NCS2SnPh3]•2CH3OH
Yin, HD
Ma, CL
Wang, Y
Fang, HX
Shao, JX
ACTA CHIMICA SINICA, 2002, 60 (05) : 897 - 903
[14] Iridium complexes with secondary phosphines: Synthesis and X-ray crystal structure of [IrCl(Bu(2)(t)PH)(3)]
Bottcher, HC
Graf, M
Merzweiler, K
POLYHEDRON, 1997, 16 (02) : 341 - 343
[15] Reactions of [IrCl(Bu-2(t)PH)(3)] with [M-3(CO)(12)](M=Fe,Ru): Synthesis and X-ray crystal structures of the metal clusters [Ru-3(CO)(8)(mu-H)(2)(mu(3)-PBut)(Bu-2(t)PH)] and [Ru3Ir(CO)(7)(mu-H)(2)(mu-PBu2t)(2)(Bu-2(t)PH)(mu(3)-Cl)]
Bottcher, HC
Graf, M
Merzweiler, K
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 531 (1-2) : 107 - 113
[16] A convenient synthesis and molecular structure of Ru(CO)3[Ph2PN( i-Bu)PPh2-P, P]
Xu, FB
Zhang, ZZ
CHINESE JOURNAL OF CHEMISTRY, 2001, 19 (05) : 528 - 529
[17] Synthesis and Properties of Ph3Sn substituted Tellurates - The Crystal Structures of trans-[(Ph3SnO)4Te(OH)2] and trans-[(Ph3SnO)2Te(OMe)4]
Herntrich, Tobias
Merzweiler, Kurt
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (05): : 803 - 807
[18] SYNTHESIS AND CHARACTERIZATION OF INDIUM THIOLATES - STRUCTURES OF [PH4P][IN(SBUT)4].CH3OH AND [PH4P][IN(SCH2CH2S)2]
HIRPO, W
SUTORIK, AC
DHINGRA, S
KANATZIDIS, MG
POLYHEDRON, 1994, 13 (19) : 2797 - 2800
[19] Synthesis, characterization and crystal structures of Ph3SnS2CN(CH3)C6H5, Ph3SnS2CN(C4H8NH) and SnCl2(S2CNEt2)2
Yin, HD
He, GF
Wang, CH
Ma, CL
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (09) : 1019 - 1024
[20] Selective synthesis of clinoatacamite Cu2(OH)3Cl and tenorite CuO nanoparticles by pH control
Engelbrekt, Christian
Malcho, Phillip
Andersen, Jonas
Zhang, Lijuan
Stahl, Kenny
Li, Bin
Hu, Jun
Zhang, Jingdong
JOURNAL OF NANOPARTICLE RESEARCH, 2014, 16 (08)

← 1 2 3 4 5 →