A singular noninterpenetrating coordination polymer with the Pt3O4 structure containing naked [Na+]4 units

被引：17
作者：
Gaspar, Ana B.
Galet, Ana
Carmen Munoz, M.
Solans, Xavier
Antonio Real, Jose
机构：
[1] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, E-46071 Valencia, Spain
[2] Univ Politecn Valencia, Dept Fis Aplicada, Valencia 46022, Spain
[3] Univ Barcelona, Fac Geol, Dept Cristallog Mineral & Deposits Minerals, E-08028 Barcelona, Spain
来源：
INORGANIC CHEMISTRY | 2006年 / 45卷 / 26期
关键词：
D O I：
10.1021/ic061797j
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The homoleptic low-spin complex [Fe(L)(3)](2+), where L is the bisbidentate ligand 1,10-phenanthroline-5,6-dione, coordinates Na+ ions via exo-oriented dione groups defining a three-dimensional cationic network {[Fe(L)(3)](4)Na-3}(11+)}(n) with Pt3O4 topology. The large volume generated by the network is filled with 11 perchlorate ions, 7 "NaClO4" ionic pairs, and 9 H2O molecules. Singular [Na+](4) units, in which the Na+ ions are practically uncoordinated, are formed.
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页码：10431 / 10433
页数：3
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