Catalytic synthesis of carbon nanotubes using zeolite support

被引：183
作者：
Hernadi, K
Fonseca, A
Nagy, JB
Bernaerts, D
Fudala, A
Lucas, AA
机构：
[1] FAC UNIV NOTRE DAME PAIX,INST STUDIES INTERFACE SCI,B-5000 NAMUR,BELGIUM
[2] UNIV SZEGED,DEPT APPL CHEM,SZEGED,HUNGARY
[3] UNIV ANTWERP,EMAT,B-2020 ANTWERP,BELGIUM
来源：
ZEOLITES | 1996年 / 17卷 / 5-6期
关键词：
carbon nanotube; catalytic synthesis; zeolite support; transition metals; nanotube purification;
D O I：
10.1016/S0144-2449(96)00088-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Catalytic synthesis of carbon nanotubes having fullerene-like structure applying supported transition metal/zeolite catalysts is introduced in this work. Decomposition of unsaturated hydrocarbons was carried out under relatively mild conditions in a fixed bed flow reactor. ?he quality of the carbon deposit was characterized by means of transmission electron microscopy. For the separation of carbon nanotubes and catalyst particles, chemical methods were applied. (C) Elsevier Science Inc. 1996
引用
收藏
页码：416 / 423
页数：8
相关论文
共 21 条
[1]   ENERGETICS OF LARGE FULLERENES - BALLS, TUBES, AND CAPSULES [J].
ADAMS, GB ;
SANKEY, OF ;
PAGE, JB ;
OKEEFFE, M ;
DRABOLD, DA .
SCIENCE, 1992, 256 (5065) :1792-1795
[2]   OPENING CARBON NANOTUBES WITH OXYGEN AND IMPLICATIONS FOR FILLING [J].
AJAYAN, PM ;
EBBESEN, TW ;
ICHIHASHI, T ;
IIJIMA, S ;
TANIGAKI, K ;
HIURA, H .
NATURE, 1993, 362 (6420) :522-525
[3]   ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC-PROPERTIES [J].
DEHEER, WA ;
BACSA, WS ;
CHATELAIN, A ;
GERFIN, T ;
HUMPHREYBAKER, R ;
FORRO, L ;
UGARTE, D .
SCIENCE, 1995, 268 (5212) :845-847
[4]   BUCKYTUBES AND DERIVATIVES - THEIR GROWTH AND IMPLICATIONS FOR BUCKYBALL FORMATION [J].
DRAVID, VP ;
LIN, X ;
WANG, Y ;
WANG, XK ;
YEE, A ;
KETTERSON, JB ;
CHANG, RPH .
SCIENCE, 1993, 259 (5101) :1601-1604
[5]   PURIFICATION OF NANOTUBES [J].
EBBESEN, TW ;
AJAYAN, PM ;
HIURA, H ;
TANIGAKI, K .
NATURE, 1994, 367 (6463) :519-519
[6]   CARBON NANOTUBES [J].
EBBESEN, TW .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1994, 24 :235-264
[7]   LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES [J].
EBBESEN, TW ;
AJAYAN, PM .
NATURE, 1992, 358 (6383) :220-222
[8]   COKING AND DEACTIVATION OF ZEOLITES - INFLUENCE OF THE PORE STRUCTURE [J].
GUISNET, M ;
MAGNOUX, P .
APPLIED CATALYSIS, 1989, 54 (01) :1-27
[9]  
HATTA N, 1994, CHEM PHYS LETT, V217, P398, DOI 10.1016/0009-2614(93)E1414-C
[10]   Catalytic synthesis and purification of carbon nanotubes [J].
Hernadi, K ;
Fonseca, A ;
Nagy, JB ;
Bernaerts, D ;
Riga, J ;
Lucas, A .
SYNTHETIC METALS, 1996, 77 (1-3) :31-34
123