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Organic cage supported metal nanoparticles for applications
被引:11
作者:
Sharma, Vivekanand
[1
]
Bharadwaj, Parimal K.
[1
]
机构:
[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, UP, India
关键词:
PALLADIUM-CATALYZED CYANATION;
GOLD NANOPARTICLES;
AMMONIA-BORANE;
HETEROGENEOUS CATALYSTS;
OPTICAL-PROPERTIES;
HYDROGEN STORAGE;
FACILE SYNTHESIS;
EFFICIENT;
METHANOLYSIS;
NANOCLUSTERS;
D O I:
10.1039/d0dt02998j
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Porous shape-persistent organic cages can anchor metal nanoparticles either inside the cavity or in the external cavity generated through self-assembly. The size of these nanoparticles range from 1-2 nm depending upon the host and can be controlled within a narrow size distribution. The nanoparticles thus formed are quite stable as they are segregated efficiently preventing their association and eventual precipitation. These fine nanoparticles are found to be quite effective in catalyzing a number of organic transformations besides showing interesting emission properties.
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页码:15574 / 15586
页数:13
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