Control of Major Carriers in an Ambipolar Polymer Semiconductor by Self-Assembled Monolayers

被引:57
作者
Nakano, Masahiro [1 ]
Osaka, Itaru [1 ]
Takimiya, Kazuo [1 ]
机构
[1] RIKEN, CEMS, 2-1 Hirosawa, Wako, Saitama 3510198, Japan
关键词
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; DONOR-ACCEPTOR POLYMER; THRESHOLD-VOLTAGE; ORGANIC TRANSISTORS; N-TYPE; CHARGE INJECTION; SPATIAL CONTROL; PERFORMANCE; DIIMIDE;
D O I
10.1002/adma.201602893
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Selective unipolarization of an ambipolar polymer semiconductor, PNDTI-BT, by using different self-assembled monolayers, is demonstrated. For p-unipolarization, 1H,1H,2H,2H-perfluorodecyltriethoxy-silane is most effective, whereas for n-unipolarization, 3-(N,N'-dimethylamino)-propyltriethoxysilane is the best. Using these selective unipolarization effects, the complementary inverters based on the ambipolar polymer fabricated by a simple solution process show greatly improved switching behaviors with low power consumption.
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页数:8
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