Three-Dimensional Ordered Macroporous Metal-Organic Framework Single Crystal-Derived Nitrogen-Doped Hierarchical Porous Carbon for High-Performance Potassium-Ion Batteries

被引:311
作者
Zhou, Xuefeng [1 ]
Chen, Lanlan [1 ]
Zhang, Wenhua [1 ,2 ,3 ]
Wang, Jiawei [4 ]
Liu, Zhenjie [4 ]
Zeng, Sifan [1 ]
Xu, Rui [1 ]
Wu, Ying [1 ]
Ye, Shufen [1 ]
Feng, Yuezhan [8 ]
Cheng, Xiaolong [1 ]
Peng, Zhangquan [4 ]
Li, Xifei [7 ]
Yu, Yan [1 ,5 ,6 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Key Lab Mat Energy Convers, Dept Mat Sci & Engn,Chinese Acad Sci, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[3] Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Anhui, Peoples R China
[4] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
[5] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
[6] Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China
[7] Xian Univ Technol, Inst Adv Electrochem Energy, Xian 710048, Shaanxi, Peoples R China
[8] Zhengzhou Univ, Key Lab Mat Proc & Mold, Minist Educ, Zhengzhou 450002, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Ordered interconnected macropores; in situ Raman spectra; carbon; nitrogen doping; potassium-ion batteries; RATE CAPABILITY; ANODE; SODIUM; NANOFIBERS; GRAPHITE; LITHIUM; INTERCALATION; ELECTRODES; GRAPHENE; STORAGE;
D O I
10.1021/acs.nanolett.9b01127
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The biggest challenge of potassium-ion batteries (KIBs) application is to develop high-performance electrode materials to accommodate the potassium ions large size. Herein, by rational design, we carbonize three-dimensional (3D) ordered macroporous ZIF-8 to fabricate 3D interconnected nitrogen-doped hierarchical porous carbon (N-HPC) that shows excellent rate performance (94 mAh g(-1) at 10.0 A g(-1)), unprecedented cycle stability (157 mA g(-1) after 12000 cycles at 2.0 A g(-1)), and superior reversible capacity (292 mAh g(-1) at 0.1 A g(-1)). The 3D hierarchical porous structure diminishes the diffusion distance for both ions/electrons, while N-doping improves the reactivity and electronic conductivity via producing more defects. In addition, the bicontinuous structure possesses a large specific surface area, decreasing the current density, again improving the rate performance. In situ Raman spectra analysis confirms the potassiation and depotassiation in the N-HPC are highly reversible processes. The galvanostatic intermittent titration measurement and first-principles calculations reveal that the interconnected macropores are more beneficial to the diffusion of the K+. This 3D interpenetrating structure demonstrates a superiority for energy storage applications.
引用
收藏
页码:4965 / 4973
页数:9
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