Chemical Equilibrium for the Reacting System Acetic Acid-Ethanol-Ethyl Acetate-Water at 303.15 K, 313.15 K and 323.15 K

被引：14

作者：

Golikova, Alexandra ^{[1
]}

Samarov, Artemiy ^{[1
]}

Trofimova, Maya ^{[1
]}

Rabdano, Sevastyan ^{[2
]}

Toikka, Maria ^{[1
]}

Pervukhin, Oleg ^{[1
]}

Toikka, Alexander ^{[1
]}

机构：

[1] St Petersburg State Univ, Dept Chem Thermodynam & Kinet, Univ Skiy Prospect 26, St Petersburg 198504, Russia

[2] St Petersburg State Univ, Lab Biomol NMR, St Petersburg 199034, Russia

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2017年 / 46卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

Chemical equilibrium; Thermodynamic constant of chemical equilibrium; Ethyl acetate; Gas chromatography; Nuclear magnetic resonance; NRTL model; VAPOR-PHASE ESTERIFICATION; LIQUID-EQUILIBRIA; DISTILLATION PROCESS; BINARY-SYSTEMS; MIXTURES; ALCOHOL;

D O I：

10.1007/s10953-017-0583-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chemical equilibrium (CE) for the quaternary reacting system ethanol-acetic acid-ethyl acetate-water was studied at 303.15, 313.15 and 323.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography and nuclear magnetic resonance analytical methods. The thermodynamic constants of CE at 303.15, 313.15 and 323.15 K were calculated based on the obtained experimental data with the use of the NRTL model.

引用

页码：374 / 387

页数：14

共 31 条

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