Synthesis of new pyrrolidine nitroxide epoxides as versatile paramagnetic building blocks

被引：7
作者：
Kálai, T
Sár, CP
Jekö, J
Hideg, K
机构：
[1] Univ Pecs, Inst Organ & Med Chem, H-7643 Pecs, Hungary
[2] ICN Hungary, H-4440 Tiszavasvari, Hungary
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 45期
基金：
匈牙利科学研究基金会;
关键词：
nitroxides; epoxides; spin labels; ring opening;
D O I：
10.1016/S0040-4039(02)01911-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Pyrrolidine nitroxide epoxides were synthesized by oxidation of the corresponding alkene, diene and alpha,beta-unsaturated aldehyde with m-CPBA or H2O2 to provide new spin labels and paramagnetic synthons. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：8125 / 8127
页数：3
相关论文
共 50 条
  • [21] 4-Iminocyclobutenones: Synthesis and Building-Blocks of Aminohydroquinones and Annulated Quinolines
    Oppermann, Gerrit
    Stranberg, Michael
    Moore, Harold W.
    Schaumann, Ernst
    Adiwidjaja, Gunadi
    SYNTHESIS-STUTTGART, 2010, (12): : 2027 - 2038
  • [22] Facile access to some chiral building blocks. Synthesis of verbalactone and exophilin A
    Wu, Jian-Zhong
    Gao, Jian
    Ren, Guo-Bao
    Zhen, Zhi-Bin
    Zhang, Yihua
    Wu, Yikang
    TETRAHEDRON, 2009, 65 (01) : 289 - 299
  • [23] Halohydrin dehalogenase-catalysed synthesis of fluorinated aromatic chiral building blocks
    Dokli, Irena
    Milcic, Nevena
    Marin, Petra
    Miklenic, Marina Svetec
    Sudar, Martina
    Tang, Lixia
    Blazevic, Zvjezdana Findrik
    Elenkov, Maja Majeric
    CATALYSIS COMMUNICATIONS, 2021, 152
  • [24] Deployment of Small-Ring Azaheterocycles as Building Blocks for the Synthesis of Organofluorine Compounds
    Dolfen, Jeroen
    De Kimpe, Norbert
    D'hooghe, Matthias
    SYNLETT, 2016, 27 (10) : 1486 - 1510
  • [25] CHIRAL EPOXIDES AS BUILDING-BLOCKS FOR ETHYLENE-BRIDGED ANSA-METALLOCENE COMPLEXES - SYNTHESIS OF C1-SYMMETRICAL ZIRCONOCENE DICHLORIDES WITH 2 DIFFERENT CYCLOPENTADIENYL UNITS
    RIEGER, B
    STEIMANN, M
    FAWZI, R
    CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (11): : 2373 - 2377
  • [26] An efficient catalyst-free ring opening of epoxides in peg-300: A versatile method for the synthesis of vicinal azidoalcohols
    A. R. Kiasat
    M. Fallah-Mehrjardi
    Journal of the Iranian Chemical Society, 2009, 6 : 542 - 546
  • [27] An Efficient Catalyst-Free Ring Opening of Epoxides in PEG-300: A Versatile Method for the Synthesis of Vicinal Azidoalcohols
    Kiasat, A. R.
    Fallah-Mehrjardi, M.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (03) : 542 - 546
  • [28] New cyclic zwitterionic building blocks for the synthesis of piperidine-2,4-dione and pyridine-2-one compounds
    Palillero, Angel
    Teran, Joel L.
    Gnecco, Dino
    Juarez, Jorge R.
    Orea, Maria L.
    Castro, Alejandro
    TETRAHEDRON LETTERS, 2009, 50 (29) : 4208 - 4211
  • [29] Recent Advances in the Green Synthesis of Heterocycles: From Building Blocks to Biologically Active Compounds
    Schafer, Christian
    Cho, Hyejin
    Vlocsko, Bernadett
    Xie, Guoshu
    Torok, Bela
    CURRENT ORGANIC SYNTHESIS, 2022, 19 (03) : 426 - 462
  • [30] Non-activated aziridines as building blocks for the synthesis of aza-heterocycles (microreview)
    Luginina, Jevgenija
    Turks, Maris
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2016, 52 (10) : 773 - 775
12345