(±)-3-Oxocyclopentanecarboxylic acid:: the smallest keto acid known to aggregate by catemeric hydrogen bonding

被引：4

作者：

Malak, Muhammad H. ^{[1
]}

Baker, Daniel ^{[1
]}

Brunskill, Andrew P. J. ^{[1
]}

Thompson, Hugh W. ^{[1
]}

Lalancette, Roger A. ^{[1
]}

机构：

[1] Rutgers State Univ, Carl A Olson Mem Labs, Dept Chem, Newark, NJ 07102 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷 / 12期

关键词：

Carboxylic acids;

D O I：

10.1107/S0108270106041369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, C6H8O3, is the smallest keto acid yet found to aggregate in the solid as acid-to-ketone hydrogen-bonded catemers. Four translational chains pass through the cell in the a direction [O center dot center dot center dot O = 2.6915 (14) A and O-H center dot center dot center dot O = 166 degrees]. Two intermolecular C-H center dot center dot center dot O close contacts exist, involving both carbonyl functions.

引用

页码：O669 / O670

页数：2

共 50 条

[1] (+)-Camphoracetic acid:: catemeric hydrogen bonding in a γ-keto acid
Thompson, HW
Coté, ML
Lalancette, RA
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : O727 - O729
[2] (±)-2-Oxocyclopentaneacetic acid: catemeric hydrogen bonding in a γ-keto acid
Efthimiopoulos, Georgia
Papadakis, Markos M.
Thompson, Hugh W.
Lalancette, Roger A.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O937 - U3542
[3] (±)-3-indanone-1-acetic acid:: Heterochiral catemeric hydrogen bonding in a δ-keto acid
Thompson, HW
Brunskill, APJ
Lalancette, RA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 829 - 831
[4] (&plusmn)-3-Indanone-1-acetic acid: Heterochiral catemeric hydrogen bonding in a δ-keto acid
Thompson, Hugh W.
Brunskill, Andrew P.J.
Lalancette, Roger A.
Acta Crystallographica, Section C: Crystal Structure Communications, 1998, 54 (pt 6): : 829 - 831
[5] (+)-3-oxo-4-pregnene-20β-carboxylic acid:: catemeric hydrogen bonding in a steroidal keto acid
Thompson, HW
Lalancette, RA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2002, 58 (01) : O22 - O23
[6] (±)-3-ethyl-2-methyl-4-oxocyclohexanecarboxylic acid:: catemeric hydrogen bonding in a cyclic δ-keto acid
Davison, M
Kikolski, EM
Lalancette, RA
Thompson, HW
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : O449 - O451
[7] 1-oxoindan-6-carboxylic acid:: catemeric hydrogen bonding in an aromatic δ-keto acid
Lalancette, Roger A.
Kikolski, Elizabeth M.
Thompson, Hugh W.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O2435 - O2437
[8] (+)-cis-Pinonic acid:: catemeric hydrogen bonding in a non-racemic ε-keto acid
Lalancette, RA
Thompson, HW
Brunskill, APJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1908 - 1911
[9] (+)-3-Oxoandrosta-1,4-diene-17β-carboxylic acid:: catemeric hydrogen bonding in a steroidal keto acid
Thompson, HW
Lalancette, RA
Brunskill, APJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1680 - 1682
[10] Santonic acid:: catemeric hydrogen bonding in a γ,ε-diketocarboxylic acid
Brunskill, APJ
Thompson, HW
Lalancette, RA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 566 - 568

← 1 2 3 4 5 →