A resin-based methodology to synthesize N-doped graphene-like metal-free catalyst for oxygen reduction

被引：19

作者：

Kang, Shuai ^{[1
]}

Shen, Pei Kang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Phys & Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2014年 / 142卷

基金：

高等学校博士学科点专项科研基金;

关键词：

N-doped grapheme-like catalyst; Ion exchange resin; Metal-free catalyst; Oxygen reduction reaction; Electrochemistry; FUEL-CELLS; CARBON; IRON; SPECTRA;

D O I：

10.1016/j.electacta.2014.07.100

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An ion-exchange resin-based methodology has been used to synthesize the N-doped graphene-like metal-free catalyst (NGMFC). This catalyst is hierarchical porous structured with high surface area. In acidic media, the NGMFC shows a high electrocatalytic performance and good stability towards oxygen reduction reaction (ORR) in rotating ring-disk electrode measurements. The onset potential of the catalyst for ORR is 0.99 V which is very close the onset potential of Pt/C catalyst. This research demonstrates that the ion-exchange resin-based methodology can be a potential alternative to produce efficient metal-free catalyst at extremely low cost for ORR. (C) 2014 Elsevier Ltd. All rights reserved.

引用

收藏

页码：182 / 186

页数：5

相关论文

共 26 条

[1] A class of non-precious metal composite catalysts for fuel cells [J].

Bashyam, Rajesh ;

Zelenay, Piotr .

NATURE, 2006, 443 (7107) :63-66

[2] Origin of the large N is binding energy in X-ray photoelectron spectra of calcined carbonaceous materials [J].

Casanovas, J ;

Ricart, JM ;

Rubio, J ;

Illas, F ;

JimenezMateos, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (34) :8071-8076

[3] ELECTROCATALYTIC OXIDATION OF NADH AND ASCORBIC-ACID ON ELECTROCHEMICALLY PRETREATED GLASSY-CARBON ELECTRODES [J].

CENAS, N ;

ROZGAITE, J ;

POCIUS, A ;

KULYS, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1983, 154 (1-2) :121-128

[4] Active and stable carbon nanotube/nanoparticle composite electrocatalyst for oxygen reduction [J].

Chung, Hoon T. ;

Won, Jong H. ;

Zelenay, Piotr .

NATURE COMMUNICATIONS, 2013, 4

[5] Interpretation of Raman spectra of disordered and amorphous carbon [J].

Ferrari, AC ;

Robertson, J .

PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107

[6] Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction [J].

Gong, Kuanping ;

Du, Feng ;

Xia, Zhenhai ;

Durstock, Michael ;

Dai, Liming .

SCIENCE, 2009, 323 (5915) :760-764

[7] Structural study of nitrogen-doping effects in bamboo-shaped multiwalled carbon nanotubes [J].

Jang, JW ;

Lee, CE ;

Lyu, SC ;

Lee, TJ ;

Lee, CJ .

APPLIED PHYSICS LETTERS, 2004, 84 (15) :2877-2879

[8] Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuel cells [J].

Jaouen, Frederic ;

Proietti, Eric ;

Lefevre, Michel ;

Chenitz, Regis ;

Dodelet, Jean-Pol ;

Wu, Gang ;

Chung, Hoon Taek ;

Johnston, Christina Marie ;

Zelenay, Piotr .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (01) :114-130

[9] Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells [J].

Lefevre, Michel ;

Proietti, Eric ;

Jaouen, Frederic ;

Dodelet, Jean-Pol .

SCIENCE, 2009, 324 (5923) :71-74

[10] Three-dimensional graphene architectures [J].

Li, Chun ;

Shi, Gaoquan .

NANOSCALE, 2012, 4 (18) :5549-5563