Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2

被引：19

作者：

Motokucho, Suguru ^{[1
]}

Morikawa, Hiroshi ^{[2
]}

机构：

[1] Nagasaki Univ, Chem & Mat Engn Program, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan

[2] Kanagawa Inst Technol, Dept Appl Chem, 1030 Shimo Ogino, Atsugi, Kanagawa 2430292, Japan

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 73期

关键词：

NON-ISOCYANATE POLYURETHANES; CHEMISTRY; RECOVERY; DIOXIDE;

D O I：

10.1039/d0cc04463f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO(2)into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields. The catalyzed reaction was applicable to various epoxides.

引用

收藏

页码：10678 / 10681

页数：4

相关论文

共 23 条

[1] En route to CO2-containing renewable materials: catalytic synthesis of polycarbonates and non-isocyanate polyhydroxyurethanes derived from cyclic carbonates [J].

Bobbink, Felix D. ;

van Muyden, Antoine P. ;

Dyson, Paul J. .

CHEMICAL COMMUNICATIONS, 2019, 55 (10) :1360-1373

[2] Recent Developments in the Synthesis of Cyclic Carbonates from Epoxides and CO2 [J].

Buettner, Hendrik ;

Longwitz, Lars ;

Steinbauer, Johannes ;

Wulf, Christoph ;

Werner, Thomas .

TOPICS IN CURRENT CHEMISTRY, 2017, 375 (03)

[3] Reprocessable polyhydroxyurethane networks exhibiting full property recovery and concurrent associative and dissociative dynamic chemistry via transcarbamoylation and reversible cyclic carbonate aminolysis [J].

Chen, Xi ;

Li, Lingqiao ;

Jin, Kailong ;

Torkelson, John M. .

POLYMER CHEMISTRY, 2017, 8 (41) :6349-6355

[4] A perspective approach to sustainable routes for non-isocyanate polyurethanes [J].

Cornille, Adrien ;

Auvergne, Remi ;

Figovsky, Oleg ;

Boutevin, Bernard ;

Caillol, Sylvain .

EUROPEAN POLYMER JOURNAL, 2017, 87 :535-552

[5] Scorpionate Catalysts for Coupling CO2 and Epoxides to Cyclic Carbonates: A Rational Design Approach for Organocatalysts [J].

Hong, Mannkyu ;

Kim, Yoseph ;

Kim, Hyejin ;

Cho, Hee Jin ;

Baik, Mu-Hyun ;

Kim, Youngjo .

JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (16) :9370-9380

[6] Biobased Reprocessable Polyhydroxyurethane Networks: Full Recovery of Crosslink Density with Three Concurrent Dynamic Chemistries [J].

Hu, Sumeng ;

Chen, Xi ;

Torkelson, John M. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (11) :10025-10034

[7] Efficient DMF-catalyzed coupling of epoxides with CO2 under solvent-free conditions to afford cyclic carbonates [J].

Jiang, Jia-Li ;

Hua, Ruimao .

SYNTHETIC COMMUNICATIONS, 2006, 36 (21) :3141-3148

[8] CO2-fixation into cyclic and polymeric carbonates: principles and applications [J].

Kamphuis, Aeilke J. ;

Picchioni, Francesco ;

Pescarmona, Paolo P. .

GREEN CHEMISTRY, 2019, 21 (03) :406-448

[9] Potassium Iodide-Tetraethylene Glycol Complex as a Practical Catalyst for CO2 Fixation Reactions with Epoxides under Mild Conditions [J].

Kaneko, Shiho ;

Shirakawa, Seiji .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (04) :2836-2840

[10] Non-isocyanate polyurethanes: from chemistry to applications [J].

Kathalewar, Mukesh S. ;

Joshi, Padmanabh B. ;

Sabnis, Anagha S. ;

Malshe, Vinod C. .

RSC ADVANCES, 2013, 3 (13) :4110-4129