Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO2

被引：21

作者：

Motokucho, Suguru ^{[1
]}

Morikawa, Hiroshi ^{[2
]}

机构：

[1] Nagasaki Univ, Chem & Mat Engn Program, 1-14 Bunkyo Machi, Nagasaki 8528521, Japan

[2] Kanagawa Inst Technol, Dept Appl Chem, 1030 Shimo Ogino, Atsugi, Kanagawa 2430292, Japan

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 73期

关键词：

NON-ISOCYANATE POLYURETHANES; CHEMISTRY; RECOVERY; DIOXIDE;

D O I：

10.1039/d0cc04463f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO(2)into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields. The catalyzed reaction was applicable to various epoxides.

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收藏

页码：10678 / 10681

页数：4

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