Facile synthesis of azo-linked porous organic frameworks via reductive homocoupling for selective CO2 capture

被引：124
|
作者：
Lu, Jingzhi [1 ]
Zhang, Jian [1 ]
机构：
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 34期
关键词：
CARBON-DIOXIDE CAPTURE; TRIAZINE-BASED FRAMEWORKS; POLYMER NETWORKS; GAS-STORAGE; DESIGN; FUNCTIONALIZATION; TEMPERATURE; ADSORPTION; H-2;
D O I：
10.1039/c4ta03015j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A facile Zn-induced reductive homocoupling reaction was used to synthesize azo-linked porous organic frameworks (azo-POFs) from easily accessed nitromonomers. Azo-POF-2 exhibits the highest CO2/N-2 selectivity of 76 at 273 K among all self-coupled azo-linked porous polymers.
引用
收藏
页码：13831 / 13834
页数：4
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