Characteristics of di- and tri-block copolymers: polymer disperse liquid crystal display

被引:10
作者
Ahmad, Farzana [1 ]
Jamil, Muhammad [2 ,3 ]
Lee, Jin Woo [1 ]
Ri, Yeo Hyo [1 ]
Jeon, Young Jae [1 ]
机构
[1] Konkuk Univ, Dept Chem, Liquid Crystal Res Ctr, Seoul, South Korea
[2] Konkuk Univ, Univ Coll, Div Int Studies, Seoul, South Korea
[3] Konkuk Univ, Dept Phys, IAP, Seoul, South Korea
关键词
polymer dispersed liquid crystal; electro-optical properties; phase separation; FTIR; PHASE-SEPARATION; FTIR SPECTROSCOPY; GRATINGS;
D O I
10.1080/09500340.2014.919037
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In the reported work the block copolymers are used in the polymer disperse liquid crystal (PDLC) films. The present work has been performed to investigate the effect of block copolymer addition and block ratios on the PDLC characteristics. From our experimental finding, addition of block copolymer in PDLC shows variation in droplet size, electro-optical properties, extent of phase separation, and phase transition temperature. These finding indicate the alteration in solubility parameters of solutions with the addition of block copolymers. Moreover, the tri-block copolymer shows enlarge droplet size, enhancement in the degree of phase separation, and predict improvement in electro-optical properties, as compared to di-block copolymer. Similarly upon such comparison, the study suggests the tri-block copolymer have a relative lower molecular interaction with the liquid crystal molecules.
引用
收藏
页码:1027 / 1032
页数:6
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