Highly tunable metal-organic frameworks with open metal centers

被引：188
作者：
Choi, Eun-Young [1 ]
Wray, Curtis A. [1 ]
Hu, Chunhua [2 ]
Choe, Wonyoung [1 ]
机构：
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
[2] NYU, Dept Chem, New York, NY 10003 USA
来源：
CRYSTENGCOMM | 2009年 / 11卷 / 04期
关键词：
HYDROGEN STORAGE; SELECTIVE SORPTION; ENANTIOSELECTIVE SORPTION; PORPHYRIN FRAMEWORK; GAS-ADSORPTION; HYBRID SOLIDS; COORDINATION; H-2; SATURATION; STRATEGIES;
D O I：
10.1039/b819707p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the synthesis and characterization of porphyrin containing metal-organic frameworks that show high metal tunability without altering the framework topology.
引用
收藏
页码：553 / 555
页数：3
相关论文
共 48 条
[1]   Optimum conditions for adsorptive storage [J].
Bhatia, SK ;
Myers, AL .
LANGMUIR, 2006, 22 (04) :1688-1700
[2]   Permanent microporosity and enantioselective sorption in a chiral open framework [J].
Bradshaw, D ;
Prior, TJ ;
Cussen, EJ ;
Claridge, JB ;
Rosseinsky, MJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114
[3]   Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal-organic framework material [J].
Chen, Banglin ;
Zhao, Xuebo ;
Putkham, Apipong ;
Hong, Kunlun ;
Lobkovsky, Emil B. ;
Hurtado, Eric J. ;
Fletcher, Ashleigh J. ;
Thomas, K. Mark .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) :6411-6423
[4]   Selective gas sorption within a dynamic metal-organic framework [J].
Chen, Banglin ;
Ma, Shengqian ;
Hurtado, Eric J. ;
Lobkovsky, Emil B. ;
Liang, Chengdu ;
Zhu, Haoguo ;
Dai, Sheng .
INORGANIC CHEMISTRY, 2007, 46 (21) :8705-8709
[5]   A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules [J].
Chen, Banglin ;
Ma, Shengqian ;
Hurtado, Eric J. ;
Lobkovsky, Emil B. ;
Zhou, Hong-Cai .
INORGANIC CHEMISTRY, 2007, 46 (21) :8490-8492
[6]   Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules [J].
Chen, Banglin ;
Ma, Shengqian ;
Zapata, Fatima ;
Fronczek, Frank R. ;
Lobkovsky, Emil B. ;
Zhou, Hong-Cai .
INORGANIC CHEMISTRY, 2007, 46 (04) :1233-1236
[7]   Hydrogen adsorption in an interpenetrated dynamic metal-organic framework [J].
Chen, Banglin ;
Ma, Shengqian ;
Zapata, Fatima ;
Lobkovsky, Emil B. ;
Yang, Jun .
INORGANIC CHEMISTRY, 2006, 45 (15) :5718-5720
[8]   High H2 adsorption in a microporous metal-organic framework with open metal sites [J].
Chen, BL ;
Ockwig, NW ;
Millward, AR ;
Contreras, DS ;
Yaghi, OM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749
[9]   A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].
Cho, So-Hye ;
Ma, Baoqing ;
Nguyen, SonBinh T. ;
Hupp, Joseph T. ;
Albrecht-Schmitt, Thomas E. .
CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565
[10]   A mixed-linker porphyrin framework with CdI2-type topology [J].
Choi, Eun-Young ;
Barron, Paul M. ;
Novotney, Richard W. ;
Hu, Chunhua ;
Kwon, Young-Uk ;
Choe, Wonyoung .
CRYSTENGCOMM, 2008, 10 (07) :824-826
12345