Synthesis, electrochemical properties, and thermal transformations of 1-(5-nitropyrimidin-2-yl)[60]fullereno[1,2-b]aziridine

被引：4
作者：
Romanova, I. P.
Yusupova, G. G.
Larionova, O. A.
Balandina, A. A.
Latypov, Sh. K.
Zverev, V. V.
Yakhvarov, D. G.
Rusinov, G. L.
Sinyashin, O. G.
机构：
[1] Russian Acad Sci, AE Arbuzov Organ & Phys Chem Inst, Kazan Res Ctr, Kazan 420088, Russia
[2] Russian Acad Sci, Ural Div, Inst Organ Synth, Ekaterinburg 620219, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2006年 / 55卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
60]fullerene; synthesis; structure; cycloaddition reactions; electrochemical properties;
D O I：
10.1007/s11172-006-0283-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of fullerene C-60 with 2-azido-5-nitropyrimidine afforded 1-(5-nitropyrimidin2-yl)[60]fullereno[1,2-b]aziridine, whose electrochemical reduction proceeds more easily than the reduction of nonmodified C-60.
引用
收藏
页码：502 / 506
页数：5
相关论文
共 19 条
[1]  
ATTAURRAHMAN, 1989, 1 2 DIMENSIONAL NMR, P579
[2]  
Averdung J, 1996, J INFORM REC, V22, P577
[3]   Exohedral functionalization of [60]fullerene by [3+2] cycloadditions: Syntheses and chemical properties of triazolino-[60]fullerenes and 1,2-(3,4-dihydro-2H-pyrrolo)-[60]fullerenes [J].
Averdung, J ;
Mattay, J .
TETRAHEDRON, 1996, 52 (15) :5407-5420
[4]   Heterocyclic and heteroatom derivatives of buckminsterfullerene C-60 [J].
BellaviaLund, C ;
KeshavarzK, M ;
Gonzalez, R ;
Hummelen, JC ;
Hicks, R ;
Wudl, F .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 120 :107-119
[5]  
Breitmaier E., 1987, Carbon-13 NMR spectroscopy
[6]  
DEROME AE, 1988, MODERN NMR TECHNIQUE
[7]  
GROSSER T, 1995, ANGEW CHEM, V107, P1462
[8]   Fast evaluation of density functional exchange-correlation terms using the expansion of the electron density in auxiliary basis sets [J].
Laikov, DN .
CHEMICAL PHYSICS LETTERS, 1997, 281 (1-3) :151-156
[9]  
Perdew JP, 1997, PHYS REV LETT, V78, P1396, DOI 10.1103/PhysRevLett.77.3865
[10]   Synthesis, properties and chemistry of aza[60]fullerene [J].
Reuther, U ;
Hirsch, A .
CARBON, 2000, 38 (11-12) :1539-1549
12