Synthesis and characterization of SBA-15 with titania clusters entrapped in micropores

被引：2
作者：
Wei Wang [1 ]
Mo Song [1 ]
机构：
[1] Univ Loughborough, Inst Polymer Technol & Engn Mat, Loughborough LE11 3TU, Leics, England
来源：
JOURNAL OF NON-CRYSTALLINE SOLIDS | 2006年 / 352卷 / 28-29期
关键词：
ceramics; Raman scattering; X-ray diffraction; scanning electron microscopy; porosity; nanoclusters;
D O I：
10.1016/j.jnoncrysol.2006.03.067
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Titania-containing SBA-15s were synthesized by impregnation of titanium isopropoxide in iso-propanol. X-ray diffraction, transmission electron microscopy, and N-2 sorption measurements showed that the mesostructures are intact after impregnations. Raman and UV-vis DRS spectra proved the existence of small anatase TiO2 clusters (similar to 1.3 nm) after three loading cycles. Disappeared micropores and unchanged mesopore volumes after three loading cycles demonstrated that majority of micropores were consumed to immobilize these small titania clusters, which could provide a new way for the development mesoporous silica-supported titania. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：3153 / 3157
页数：5
相关论文
共 50 条
  • [41] Functionalized SBA-15 organosilicas as sorbents of mercury(II), cadmium(II) and copper(II)
    Barczak, M.
    Oszust, M.
    Michalak, K.
    Gdula, K.
    Pasieczna-Patkowska, S.
    Zieba, E.
    Dabrowski, A.
    GLASS PHYSICS AND CHEMISTRY, 2014, 40 (01) : 41 - 48
  • [42] Effect of Confinement on the Fluid Properties of Ammonia in Mesopores of MCM-41 and SBA-15
    Kittaka, Shigeharu
    Morimura, Mayura
    Ishimaru, Shinji
    Morino, Akiko
    Ueda, Kyoko
    LANGMUIR, 2009, 25 (03) : 1718 - 1724
  • [43] Functionalized SBA-15 organosilicas as sorbents of mercury(II), cadmium(II) and copper(II)
    M. Barczak
    M. Oszust
    K. Michalak
    K. Gdula
    S. Pasieczna-Patkowska
    E. Zięba
    A. Dąbrowski
    Glass Physics and Chemistry, 2014, 40 : 41 - 48
  • [44] Encapsulation of Nitrate Ester Nanoparticles Into the SBA-15 Channels: Preparation, Characterizations and Reaction Mechanism
    Tian, Li
    Tao, Guo-Hong
    Cai, Hua-Qiang
    ADVANCED POROUS MATERIALS, 2014, 2 (01) : 22 - 30
  • [45] Synthesis of pure rod-like α-Si3N4 powder with in situ C/SBA-15 composite
    Zhou, Yao
    Liu, Qian
    Zhou, Hu
    CERAMICS INTERNATIONAL, 2012, 38 (07) : 6059 - 6062
  • [46] N-BOC protection of amines over mesoporous SBA-15 catalyst at room temperature
    Viswanadham, Balaga
    Tejeswararao, Dharmana
    Putrakumar, Balla
    JOURNAL OF POROUS MATERIALS, 2023, 30 (03) : 713 - 721
  • [47] Studies of the structure and chemistry of SBA-15 organosilicas functionalized with amine, thiol, vinyl and phenyl groups
    Mariusz Barczak
    Andrzej Dąbrowski
    Stanisław Pikus
    Janusz Ryczkowski
    Piotr Borowski
    Maciej Kozak
    Adsorption, 2010, 16 : 457 - 463
  • [48] Studies of the structure and chemistry of SBA-15 organosilicas functionalized with amine, thiol, vinyl and phenyl groups
    Barczak, Mariusz
    Dabrowski, Andrzej
    Pikus, Stanislaw
    Ryczkowski, Janusz
    Borowski, Piotr
    Kozak, Maciej
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2010, 16 (4-5): : 457 - 463
  • [49] Features of the Real Structure of Metallic Silver Nanoparticles Located in Channels of Mesoporous Silicate SBA-15
    D. A. Zyuzin
    S. V. Cherepanova
    E. M. Moroz
    B. L. Moroz
    E. Yu. Gerasimov
    V. I. Bukhtiyarov
    Journal of Structural Chemistry, 2019, 60 : 2015 - 2024
  • [50] N-BOC protection of amines over mesoporous SBA-15 catalyst at room temperature
    Balaga Viswanadham
    Dharmana Tejeswararao
    Balla Putrakumar
    Journal of Porous Materials, 2023, 30 : 713 - 721
12345