Nitrous oxide mediated oxygen atom insertion into a ruthenium-hydride bond. Synthesis and reactivity of the monomeric hydroxoruthenium complex (DMPE)(2)Ru(H)(OH)

被引：59

作者：

Kaplan, AW ^{[1
]}

Bergman, RG ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 06期

关键词：

D O I：

10.1021/om960991i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of (DMPE)(2)Ru(H)(2) with 1 equiv of N2O affords the hydroxoruthenium complex (DMPE)(2)Ru(H)(OH) (1) in 41% yield; further treatment with an atmosphere of N2O affords the bis(hydroxo) complex (DMPE)(2)Ru(OH)(2) (4) in 17% yield. The addition of protic reagents to 1 results in the replacement of the OH group with several other ligands, including aryloxo, thiolato, siloxo, C-bound enolate, acetylide, and triphenylstannyl; more deep-seated changes take place when 1 reacts with p-tolualdehyde and hexafluoroacetone.

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页码：1106 / 1108

页数：3

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