A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

被引：144

作者：

Gadzikwa, Tendai ^{[1
,2
]}

Farha, Omar K. ^{[1
,2
]}

Mulfort, Karen L. ^{[1
,2
,3
]}

Hupp, Joseph T. ^{[1
,2
]}

Nguyen, SonBinh T. ^{[1
,2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Inst Catalysis Energy Proc, Evanston, IL 60208 USA

[3] Argonne Natl Lab, Div Chem Sci & Engn, Argonne, IL 60439 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 25期

关键词：

METAL-ORGANIC FRAMEWORK; SELECTIVE SORPTION; COORDINATION; SEPARATION; FUNCTIONALIZATION; CATALYSIS; BINDING; LIGAND; HYDROCARBONS; REDUCTION;

D O I：

10.1039/b823392f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.

引用

页码：3720 / 3722

页数：3

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