New hydrogen-bonded donor-acceptor pairs between dipyridylacetylenes and 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone

被引:62
作者
Zaman, MB [1 ]
Tomura, M
Yamashita, Y
机构
[1] Res Ctr Mol Mat, Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Univ Dhaka, Dept Appl Chem & Chem Technol, Dhaka 1000, Bangladesh
关键词
D O I
10.1021/ol991229q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The crystalline donor-acceptor hydrogen-bonding complexes between 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone (chloranilic acid) and dipyridylacetylenes (DPA) [2,2'-DPA, 3,3'-DPA, and 4,4'-DPA] were prepared, and crystal structures were revealed by X-ray analysis. The structures of the complexes are formed by intermolecular hydrogen-bonding interactions and demonstrate three supramolecular architectures based on a new common supramolecular synthon, which allows the formation of a different stacking arrangement and ionicity.
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收藏
页码:273 / 275
页数:3
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