Aerobic cross-dehydrogenative coupling of terminal alkynes and tertiary amines by a combined catalyst of Zn2+ and OMS-2

被引：22
作者：
Jin, Xiongjie [1 ]
Yamaguchi, Kazuya [1 ]
Mizuno, Noritaka [1 ]
机构：
[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
来源：
RSC ADVANCES | 2014年 / 4卷 / 65期
基金：
日本学术振兴会;
关键词：
C-H BONDS; ONE-POT SYNTHESIS; PROPARGYLIC AMINES; VISIBLE-LIGHT; IN-SITU; ENANTIOSELECTIVE SYNTHESIS; DIRECT-ADDITION; NITROGEN ATOM; ACTIVATION; OXIDATION;
D O I：
10.1039/c4ra05105j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the presence of ZnBr2 and a manganese oxide-based octahedral molecular sieve (OMS-2), cross-dehydrogenative coupling of a wide range of terminal alkynes and tertiary amines to propargylamines efficiently proceeded using molecular oxygen as the terminal oxidant.
引用
收藏
页码：34712 / 34715
页数：4
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