Sorption of Water, Methanol, and Hexane Vapors by Crystalline Carboxylates of bis-Macrocyclic Copper(II) Complexes

被引：0
作者：
Tsymbal, L. V. [1 ]
Andriichuk, I. L. [1 ]
Yaremov, P. S. [1 ]
Ilyin, V. G. [1 ]
Lampeka, Ya. D. [1 ]
机构：
[1] Natl Acad Sci Ukraine, LV Pisarzhevskii Inst Phys Chem, UA-03028 Kiev, Ukraine
来源：
THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2014年 / 50卷 / 04期
关键词：
copper(II); macrocyclic complexes; aromatic carboxylates; adsorption; water; methanol; hexane; METAL-ORGANIC FRAMEWORKS; PROTON CONDUCTION; ADSORPTION; HYDROGEN; ALCOHOLS; STORAGE;
D O I：
10.1007/s11237-014-9367-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have established that a typical feature of adsorption processes involving participation of porous ionic crystalline compounds formed by cations of bis-macrocyclic copper(II) complexes is absorption/desorption hysteresis, associated with significant rearrangement of the lattices of the complexes during adsorption/desorption. The compounds studied have high sorption capacity for water and methanol, comparable with that of porous coordination polymers.
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页码：250 / 256
页数：7
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