Fabrication of Continuous and Segmented Polymer/Metal Oxide Nanowires Using Cylindrical Micelles and Block Comicelles as Templates

被引:93
作者
Wang, Hai [2 ]
Patil, Avinash J. [1 ]
Liu, Kun [2 ]
Petrov, Srebri [2 ]
Mann, Stephen [1 ]
Winnik, Mitchell A. [2 ]
Manners, Ian [1 ,2 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
关键词
CORE-SHELL; COPOLYMER MICELLES; NANOPARTICLES; WIRE; NANOSTRUCTURES; MORPHOLOGIES; NANOFIBERS; NANOTUBES; BRUSHES; SPHERES;
D O I
10.1002/adma.200803015
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cylindrical micelles were added as templates to sol-gel reaction mixtures to yield plates to sol highly elongated polymer/inorganic nanostructures with smooth nanothin surface coatings of silica, zirconia, or alumina. Differences in the templating activity of neutral or cationic coronas can be exploited by using triblock comicelles to produce discrete nanocylinders with spatially isolated domains of titania surface deposition.
引用
收藏
页码:1805 / +
页数:5
相关论文
共 35 条
  • [21] Redox-mediated synthesis and encapsulation of inorganic nanoparticles in shell-cross-linked cylindrical polyferrocenylsilane block copolymer micelles
    Wang, Hai
    Wang, Xiaosong
    Winnik, Mitchell A.
    Manners, Ian
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (39) : 12921 - 12930
  • [22] Cylindrical block co-micelles with spatially selective functionalization by nanoparticles
    Wang, Hai
    Lin, Wanjuan
    Fritz, Karolina P.
    Scholes, Gregory D.
    Winnik, Mitchell A.
    Manners, Ian
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) : 12924 - +
  • [23] Synthesis and self-assembly of poly(ferrocenyldimethylsilane-b-2-vinylpyridine) diblock copolymers
    Wang, Hai
    Winnik, Mitchell A.
    Manners, Ian
    [J]. MACROMOLECULES, 2007, 40 (10) : 3784 - 3789
  • [24] Cylindrical block copolymer micelles and co-micelles of controlled length and architecture
    Wang, Xiaosong
    Guerin, Gerald
    Wang, Hai
    Wang, Yishan
    Manners, Ian
    Winnik, Mitchell A.
    [J]. SCIENCE, 2007, 317 (5838) : 644 - 647
  • [25] Swellable, redox-active shell-crosslinked organometallic nanotubes
    Wang, XS
    Winnik, MA
    Manners, I
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (28) : 3703 - 3707
  • [26] Wang ZL, 2000, ADV MATER, V12, P1295, DOI 10.1002/1521-4095(200009)12:17<1295::AID-ADMA1295>3.0.CO
  • [27] 2-B
  • [28] One-dimensional nanostructures: Synthesis, characterization, and applications
    Xia, YN
    Yang, PD
    Sun, YG
    Wu, YY
    Mayers, B
    Gates, B
    Yin, YD
    Kim, F
    Yan, YQ
    [J]. ADVANCED MATERIALS, 2003, 15 (05) : 353 - 389
  • [29] Silica structures templated on fibers of tetraalkylphosphonium salt gelators in organogels
    Xiao Huang
    Weiss, Richard G.
    [J]. LANGMUIR, 2006, 22 (20) : 8542 - 8552
  • [30] Water-dispersible polymer/Pd/Ni hybrid magnetic nanofibers
    Yan, XH
    Liu, GJ
    Haeussler, M
    Tang, BZ
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (24) : 6053 - 6059